Octacyanometallate qubit candidates

Tyler J. Pearson, Daniel W. Laorenza, Matthew D. Krzyaniak, Michael R. Wasielewski, Danna E. Freedman*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3- and [W(CN)8]3-. At 5 K, these complexes display remarkably long spin-lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin-orbit coupling as a handle to tune vibrationally mediated spin-lattice relaxation.

Original languageEnglish (US)
Pages (from-to)11744-11748
Number of pages5
JournalDalton Transactions
Volume47
Issue number34
DOIs
StatePublished - 2018

ASJC Scopus subject areas

  • Inorganic Chemistry

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