@article{d29a91b83441474baa7c32b576db9585,
title = "Octacyanometallate qubit candidates",
abstract = "We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3- and [W(CN)8]3-. At 5 K, these complexes display remarkably long spin-lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin-orbit coupling as a handle to tune vibrationally mediated spin-lattice relaxation.",
author = "Pearson, {Tyler J.} and Laorenza, {Daniel W.} and Krzyaniak, {Matthew D.} and Wasielewski, {Michael R.} and Freedman, {Danna E}",
note = "Funding Information: We thank C. J. Yu for experimental assistance and helpful discussions. We further acknowledge assistance from M. S. Fataftah for insightful discussions into relaxation processes and for editing. This research was conducted with the support of the National Science Foundation for CAREER award CHE-1455017 (D. W. L. and D. E. F.), and the Presidential Early Career Award for Scientists and Engineers (FA9550-17-1-0247) (D. E. F.). This work was also supported by the National Science Foundation under grant no. CHE-1565925 (M. R. W.). T. J. P. recognises the support of an NSF Graduate Research Fellowship (DGE-1324585). Funding Information: This research was conducted with the support of the National Science Foundation for CAREER award CHE-1455017 (D. W. L. and D. E. F.), and the Presidential Early Career Award for Scientists and Engineers (FA9550-17-1-0247) (D. E. F.). This work was also supported by the National Science Foundation under grant no. CHE-1565925 (M. R. W.). T. J. P. recognises the support of an NSF Graduate Research Fellowship (DGE-1324585). Publisher Copyright: {\textcopyright} 2018 The Royal Society of Chemistry.",
year = "2018",
doi = "10.1039/c8dt02312c",
language = "English (US)",
volume = "47",
pages = "11744--11748",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "34",
}