Octahedral molybdenum cluster cyanide complexes with selenide and halide ligands in the cluster core

Yuri V. Mironov; Vladimir N. Ikorskii; Vladimir E. Fedorov; James A. Ibers

doi:10.1002/ejic.200400497

Octahedral molybdenum cluster cyanide complexes with selenide and halide ligands in the cluster core

Yuri V. Mironov, Vladimir N. Ikorskii, Vladimir E. Fedorov, James A. Ibers^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

Two new octahedral molybdenum cluster cyanide complexes with mixed selenide/halide ligands in the cluster core, Cs₅[Mo ₆Se_3.6Cl_4.4(CN)₆] (1) and Cs ₅[Mo₆Se_3.4Br_4.6(CN)₆] (2), have been synthesized by the reaction of Mo₆Cl₁₂ or Mo₆Br₁₂ with an aqueous solution of Cs₂Se ₃, and then with an aqueous solution of KCN. Both compounds have been characterized by single-crystal X-ray diffraction methods. The compounds are isostructural and crystallize in the trigonal space group P3c1 with two formula units per unit cell. The unit cell dimensions at 153 K are a = 9.8895(9) Å, c = 19.395(3) Å, V = 1642.7(3) Å³ (1) and a = 9.9805(9) Å, c = 19.763(2) Å, V = 1704.9(3) Å³ (2).

Original language	English (US)
Pages (from-to)	214-217
Number of pages	4
Journal	European Journal of Inorganic Chemistry
Issue number	1
DOIs	https://doi.org/10.1002/ejic.200400497
State	Published - Jan 7 2005
Externally published	Yes

Keywords

Chalcohalide
Clusters
Cyanide
Molybdenum
Solid-state structures

ASJC Scopus subject areas

Inorganic Chemistry

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@article{c822f163051b4b628d4bedb882657175,

title = "Octahedral molybdenum cluster cyanide complexes with selenide and halide ligands in the cluster core",

abstract = "Two new octahedral molybdenum cluster cyanide complexes with mixed selenide/halide ligands in the cluster core, Cs5[Mo 6Se3.6Cl4.4(CN)6] (1) and Cs 5[Mo6Se3.4Br4.6(CN)6] (2), have been synthesized by the reaction of Mo6Cl12 or Mo6Br12 with an aqueous solution of Cs2Se 3, and then with an aqueous solution of KCN. Both compounds have been characterized by single-crystal X-ray diffraction methods. The compounds are isostructural and crystallize in the trigonal space group P3c1 with two formula units per unit cell. The unit cell dimensions at 153 K are a = 9.8895(9) {\AA}, c = 19.395(3) {\AA}, V = 1642.7(3) {\AA}3 (1) and a = 9.9805(9) {\AA}, c = 19.763(2) {\AA}, V = 1704.9(3) {\AA}3 (2).",

keywords = "Chalcohalide, Clusters, Cyanide, Molybdenum, Solid-state structures",

author = "Mironov, {Yuri V.} and Ikorskii, {Vladimir N.} and Fedorov, {Vladimir E.} and Ibers, {James A.}",

year = "2005",

month = jan,

day = "7",

doi = "10.1002/ejic.200400497",

language = "English (US)",

pages = "214--217",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

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TY - JOUR

T1 - Octahedral molybdenum cluster cyanide complexes with selenide and halide ligands in the cluster core

AU - Mironov, Yuri V.

AU - Ikorskii, Vladimir N.

AU - Fedorov, Vladimir E.

AU - Ibers, James A.

PY - 2005/1/7

Y1 - 2005/1/7

N2 - Two new octahedral molybdenum cluster cyanide complexes with mixed selenide/halide ligands in the cluster core, Cs5[Mo 6Se3.6Cl4.4(CN)6] (1) and Cs 5[Mo6Se3.4Br4.6(CN)6] (2), have been synthesized by the reaction of Mo6Cl12 or Mo6Br12 with an aqueous solution of Cs2Se 3, and then with an aqueous solution of KCN. Both compounds have been characterized by single-crystal X-ray diffraction methods. The compounds are isostructural and crystallize in the trigonal space group P3c1 with two formula units per unit cell. The unit cell dimensions at 153 K are a = 9.8895(9) Å, c = 19.395(3) Å, V = 1642.7(3) Å3 (1) and a = 9.9805(9) Å, c = 19.763(2) Å, V = 1704.9(3) Å3 (2).

AB - Two new octahedral molybdenum cluster cyanide complexes with mixed selenide/halide ligands in the cluster core, Cs5[Mo 6Se3.6Cl4.4(CN)6] (1) and Cs 5[Mo6Se3.4Br4.6(CN)6] (2), have been synthesized by the reaction of Mo6Cl12 or Mo6Br12 with an aqueous solution of Cs2Se 3, and then with an aqueous solution of KCN. Both compounds have been characterized by single-crystal X-ray diffraction methods. The compounds are isostructural and crystallize in the trigonal space group P3c1 with two formula units per unit cell. The unit cell dimensions at 153 K are a = 9.8895(9) Å, c = 19.395(3) Å, V = 1642.7(3) Å3 (1) and a = 9.9805(9) Å, c = 19.763(2) Å, V = 1704.9(3) Å3 (2).

KW - Chalcohalide

KW - Clusters

KW - Cyanide

KW - Molybdenum

KW - Solid-state structures

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U2 - 10.1002/ejic.200400497

DO - 10.1002/ejic.200400497

M3 - Article

AN - SCOPUS:12344254042

SN - 1434-1948

SP - 214

EP - 217

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 1

ER -

Octahedral molybdenum cluster cyanide complexes with selenide and halide ligands in the cluster core

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Keywords

ASJC Scopus subject areas

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