Octanuclear Heterometallic Clusters with Rhombic Dodecahedral Cores. The Synthesis, Structural Characterization, and Properties of the {Fe6S6(p-RPhO)6[M(CO)3]2}n− Clusters (M = Mo, n = 3, R = Me, OMe, NMe2; M = W, n = 3, R = Me; M = Mo, n = 4, R = Me, OMe, COMe). Precursors for Synthetic Analogues for the Fe/Mo/S Site in Nitrogenase

S. A. Al-Ahmad, A. Salifoglou, M. G. Kanatzidis, W. R. Dunham, D. Coucouvanis

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Chemistry