Octathioporphyrazine Crown Ethers: An Octanuclear AgI Complex with Coordination in the meso Pocket

John W. Sibert, Steven J. Lange, Charlotte L. Stern, A. G.M. Barrett*, Brian M Hoffman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

44 Scopus citations

Abstract

Two distinct types of peripheral binding site coordinate the eight Ag1 ions in the complex cation 1. The four crown ether units each coordinate one Ag1 atom. Each of the other four Ag1 ions binds in a meso pocket that is formed by a meso N atom and two S atoms attached to the adjacent Cβ positions. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)2020-2022
Number of pages3
JournalAngewandte Chemie International Edition in English
Volume34
Issue number18
DOIs
StatePublished - Oct 2 1995

Keywords

  • coordination
  • crown ethers
  • porphyrazines
  • silver compounds

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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