On the Failure of the Guidry-Drago Reanalysis of Spectroscopic Data for the Reversible Oxygenation of Amine Complexes of Cobalt Protoporphyrin IX Dimethyl Ester

James A Ibers, Dennis V. Stynes, H. Cleary Stynes, Brian R. James

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

The reanalysis by Guidry and Drago of our spectroscopic data for the reversible oxygenation of amine complexes of cobalt protoporphyrin IX dimethyl ester is examined and shown to lack any redeeming features. A least-squares analysis is presented which supports our earlier analysis and which demonstrates the failure of the various empirical rules devised by Drago and coworkers for the assessment of spectroscopic data. Despite the general success of the least-squares approach used here for the simultaneous determination of the equilibrium constant and the molar absorptivity of the oxygenated species, arguments are presented in favor of our previous procedure of using limiting spectra in the derivation of the equilibrium constant.

Original languageEnglish (US)
Pages (from-to)1358-1363
Number of pages6
JournalJournal of the American Chemical Society
Volume96
Issue number5
DOIs
StatePublished - Mar 1 1974

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Oxygenation
Equilibrium constants
Least-Squares Analysis
Amines
Cobalt
Esters
dimethyl protoporphyrin IX
cobaltiprotoporphyrin

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

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title = "On the Failure of the Guidry-Drago Reanalysis of Spectroscopic Data for the Reversible Oxygenation of Amine Complexes of Cobalt Protoporphyrin IX Dimethyl Ester",
abstract = "The reanalysis by Guidry and Drago of our spectroscopic data for the reversible oxygenation of amine complexes of cobalt protoporphyrin IX dimethyl ester is examined and shown to lack any redeeming features. A least-squares analysis is presented which supports our earlier analysis and which demonstrates the failure of the various empirical rules devised by Drago and coworkers for the assessment of spectroscopic data. Despite the general success of the least-squares approach used here for the simultaneous determination of the equilibrium constant and the molar absorptivity of the oxygenated species, arguments are presented in favor of our previous procedure of using limiting spectra in the derivation of the equilibrium constant.",
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On the Failure of the Guidry-Drago Reanalysis of Spectroscopic Data for the Reversible Oxygenation of Amine Complexes of Cobalt Protoporphyrin IX Dimethyl Ester. / Ibers, James A; Stynes, Dennis V.; Stynes, H. Cleary; James, Brian R.

In: Journal of the American Chemical Society, Vol. 96, No. 5, 01.03.1974, p. 1358-1363.

Research output: Contribution to journalArticle

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