On the origin of ferromagnetism in oximato-based [Mn3O] 7+ triangles

Joan Cano*, Thomas Cauchy, Eliseo Ruiz, Constantinos J. Milios, Constantinos C. Stoumpos, Theocharis C. Stamatatos, Spyros P. Perlepes, George Christou, Euan K. Brechin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

Original languageEnglish (US)
Pages (from-to)234-240
Number of pages7
JournalDalton Transactions
Issue number2
DOIs
StatePublished - Jan 1 2008

ASJC Scopus subject areas

  • Inorganic Chemistry

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