On the origin of ferromagnetism in oximato-based [Mn3O] 7+ triangles

Joan Cano; Thomas Cauchy; Eliseo Ruiz; Constantinos J. Milios; Constantinos C. Stoumpos; Theocharis C. Stamatatos; Spyros P. Perlepes; George Christou; Euan K. Brechin

doi:10.1039/b710055h

On the origin of ferromagnetism in oximato-based [Mn₃O] ⁷⁺ triangles

Joan Cano^*, Thomas Cauchy, Eliseo Ruiz, Constantinos J. Milios, Constantinos C. Stoumpos, Theocharis C. Stamatatos, Spyros P. Perlepes, George Christou, Euan K. Brechin

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered Mn^III triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

Original language	English (US)
Pages (from-to)	234-240
Number of pages	7
Journal	Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/b710055h
State	Published - Jan 1 2008

ASJC Scopus subject areas

Inorganic Chemistry

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title = "On the origin of ferromagnetism in oximato-based [Mn3O] 7+ triangles",

abstract = "DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.",

author = "Joan Cano and Thomas Cauchy and Eliseo Ruiz and Milios, {Constantinos J.} and Stoumpos, {Constantinos C.} and Stamatatos, {Theocharis C.} and Perlepes, {Spyros P.} and George Christou and Brechin, {Euan K.}",

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On the origin of ferromagnetism in oximato-based [Mn₃O] ⁷⁺ triangles. / Cano, Joan; Cauchy, Thomas; Ruiz, Eliseo; Milios, Constantinos J.; Stoumpos, Constantinos C.; Stamatatos, Theocharis C.; Perlepes, Spyros P.; Christou, George; Brechin, Euan K.

In: Dalton Transactions, No. 2, 01.01.2008, p. 234-240.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - On the origin of ferromagnetism in oximato-based [Mn3O] 7+ triangles

AU - Cano, Joan

AU - Cauchy, Thomas

AU - Ruiz, Eliseo

AU - Milios, Constantinos J.

AU - Stoumpos, Constantinos C.

AU - Stamatatos, Theocharis C.

AU - Perlepes, Spyros P.

AU - Christou, George

AU - Brechin, Euan K.

PY - 2008/1/1

Y1 - 2008/1/1

N2 - DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

AB - DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

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