On the origin of ferromagnetism in oximato-based [Mn3O]7+ triangles

Joan Cano*, Thomas Cauchy, Eliseo Ruiz, Constantinos J. Milios, Constantinos C. Stoumpos, Theocharis C. Stamatatos, Spyros P. Perlepes, George Christou, Euan K. Brechin

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

52 Scopus citations

Abstract

DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the ‘non-planarity’ of the bridging oxime ligands and the non-parallel alignment of the Jahn–Teller axes.

Original languageEnglish (US)
Pages (from-to)234-240
Number of pages7
JournalJournal of the Chemical Society. Dalton Transactions
Issue number2
DOIs
StatePublished - Oct 19 2007

ASJC Scopus subject areas

  • Chemistry(all)

Fingerprint

Dive into the research topics of 'On the origin of ferromagnetism in oximato-based [Mn3O]7+ triangles'. Together they form a unique fingerprint.

Cite this