On the origin of ferromagnetism in oximato-based [Mn3O] 7+ triangles

Joan Cano; Thomas Cauchy; Eliseo Ruiz; Constantinos J. Milios; Constantinos C. Stoumpos; Theocharis C. Stamatatos; Spyros P. Perlepes; George Christou; Euan K. Brechin

doi:10.1039/b710055h

On the origin of ferromagnetism in oximato-based [Mn₃O] ⁷⁺ triangles

Joan Cano^*, Thomas Cauchy, Eliseo Ruiz, Constantinos J. Milios, Constantinos C. Stoumpos, Theocharis C. Stamatatos, Spyros P. Perlepes, George Christou, Euan K. Brechin

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered Mn^III triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

Original language	English (US)
Pages (from-to)	234-240
Number of pages	7
Journal	Dalton Transactions
Issue number	2
DOIs	https://doi.org/10.1039/b710055h
State	Published - 2008

ASJC Scopus subject areas

Inorganic Chemistry

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10.1039/b710055h

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title = "On the origin of ferromagnetism in oximato-based [Mn3O] 7+ triangles",

abstract = "DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.",

author = "Joan Cano and Thomas Cauchy and Eliseo Ruiz and Milios, {Constantinos J.} and Stoumpos, {Constantinos C.} and Stamatatos, {Theocharis C.} and Perlepes, {Spyros P.} and George Christou and Brechin, {Euan K.}",

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doi = "10.1039/b710055h",

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AU - Cano, Joan

AU - Cauchy, Thomas

AU - Ruiz, Eliseo

AU - Milios, Constantinos J.

AU - Stoumpos, Constantinos C.

AU - Stamatatos, Theocharis C.

AU - Perlepes, Spyros P.

AU - Christou, George

AU - Brechin, Euan K.

PY - 2008

Y1 - 2008

N2 - DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

AB - DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered MnIII triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.

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DO - 10.1039/b710055h

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SN - 1477-9226

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JO - Dalton Transactions

JF - Dalton Transactions

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ER -

On the origin of ferromagnetism in oximato-based [Mn₃O] ⁷⁺ triangles

Abstract

ASJC Scopus subject areas

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