Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang; Debajit Sarma; Ya Qin Wu; Li Wang; Zhi Xue Ning; Fu Qiang Zhang; Mercouri G. Kanatzidis

doi:10.1021/jacs.6b02959

Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals

Xian Ming Zhang^*, Debajit Sarma, Ya Qin Wu, Li Wang, Zhi Xue Ning, Fu Qiang Zhang, Mercouri G. Kanatzidis

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

97 Scopus citations

Abstract

The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

Original language	English (US)
Pages (from-to)	5543-5546
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	17
DOIs	https://doi.org/10.1021/jacs.6b02959
State	Published - May 4 2016

Funding

This work was financially supported by 10,000 Talent Plan, NSFC (2095101, 21371147, 21365021), the Ministry of Education of China (no. IRT1156), and XJOYF (grant no. 2013711009). At Northwestern this research was supported by the National Science Foundation (Grant DMR-1410169).

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.6b02959

Cite this

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title = "Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals",

abstract = "The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.",

author = "Zhang, {Xian Ming} and Debajit Sarma and Wu, {Ya Qin} and Li Wang and Ning, {Zhi Xue} and Zhang, {Fu Qiang} and Kanatzidis, {Mercouri G.}",

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AU - Zhang, Xian Ming

AU - Sarma, Debajit

AU - Wu, Ya Qin

AU - Wang, Li

AU - Ning, Zhi Xue

AU - Zhang, Fu Qiang

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: This work was financially supported by 10,000 Talent Plan, NSFC (2095101, 21371147, 21365021), the Ministry of Education of China (no. IRT1156), and XJOYF (grant no. 2013711009). At Northwestern this research was supported by the National Science Foundation (Grant DMR-1410169). Publisher Copyright: © 2016 American Chemical Society.

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Y1 - 2016/5/4

N2 - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

AB - The new ion-exchange oxy-sulfide material has a three-dimensional open framework comprising the pseudo-T4 supertetrahedral [In4Sn16O10S34]12- cluster. This material has large pores and is a fast ion exchanger. It exhibits high selectivity in sequestering heavy metal ions from aqueous solutions including solutions containing heavy concentrations of sodium, calcium, ammonium, magnesium, zinc, carbonate, phosphate, and acetate ions. Moreover, the ion-exchange efficiency in competitive ionexchange experiments involving mixtures of metal ions is significantly higher than for solutions of single metal ions.

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Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals

Abstract

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ASJC Scopus subject areas

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CCDC 1015390: Experimental Crystal Structure Determination

Cite this

Open-framework oxysulfide based on the supertetrahedral [In4Sn16O10S34]12- cluster and efficient sequestration of heavy metals

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

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CCDC 1015390: Experimental Crystal Structure Determination

Cite this

Open-framework oxysulfide based on the supertetrahedral [In₄Sn₁₆O₁₀S₃₄]^12- cluster and efficient sequestration of heavy metals