Organo-fⁿ,d⁰-mediated synthesis of amine-capped polyethylenes. Scope and mechanism

Keyphrases

• Amines 100%
• Organo 100%
• Polyethylene 100%
• Mediated Synthesis 100%
• Trimethylsilyl 36%
• Chain Transfer 27%
• Chain Transfer Agent 27%
• Dicyclohexylamine 27%
• Ethylene 18%
• Polymerization Process 18%
• Polymer Chain 18%
• Ethylene Polymerization 18%
• Tert-butyl 18%
• Isopropylamine 18%
• Chain Growth 18%
• Sec-butylamine 18%
• Transfer Efficiency 9%
• Polydispersity 9%
• High Molecular Weight 9%
• Reinitiation 9%
• Well-behaved 9%
• Polyolefins 9%
• Organolanthanide 9%
• Precatalyst 9%
• Acidity 9%
• Linear Relationship 9%
• Structure H 9%
• Protonolysis 9%
• Olefin Polymerization 9%
• Secondary Amines 9%
• Primary Amines 9%
• Polymerization Activity 9%
• Transfer Path 9%
• Chain Termination 9%
• Propylene Polymerization 9%
• Aniline 9%
• Propylamine 9%
• Polymerization Rate 9%
• Aminolysis 9%

Chemistry

• Polymerization 100%
• Ethylene 66%
• Dicyclohexylamine 50%
• Polymer Chain 33%
• Isopropylamine 33%
• Sec-Butylamine 33%
• Propene 16%
• Alkene 16%
• Primary Amine 16%
• Secondary Amine 16%
• Polydispersity 16%
• Molecular Mass 16%
• Propylamine 16%
• Aminolysis 16%
• Isopropyl Group 16%
• pre-catalyst 16%
• acidity 16%
• Polyolefin 16%
• Dideoxynucleotide Sequencing 16%

Chemical Engineering

• Polymerization 100%
• Ethylene 80%
• Olefin 20%
• Propylene 20%
• Polyolefin 20%
• Polymerization Rate 20%