Organolanthanide-centered hydroamination/cyclizatlon of aminoolefins. Expedient oxidative access to catalytic cycles

Michel R. Gagné; Steven P. Nolan; Tobin J. Marks

doi:10.1021/om00156a005

Organolanthanide-centered hydroamination/cyclizatlon of aminoolefins. Expedient oxidative access to catalytic cycles

Michel R. Gagné, Steven P. Nolan, Tobin J. Marks^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

165 Scopus citations

Abstract

The readily accessible (Me₅C₅)₂Sm and (Me₅C_s)₂Sm(THF)2 catalyze the hydroaminatton/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organo-samarium complexes.

Original language	English (US)
Pages (from-to)	1716-1718
Number of pages	3
Journal	Organometallics
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/om00156a005
State	Published - 1990

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{b7ff864633734f7bb45fc671cdb17fc9,

title = "Organolanthanide-centered hydroamination/cyclizatlon of aminoolefins. Expedient oxidative access to catalytic cycles",

abstract = "The readily accessible (Me5C5)2Sm and (Me5Cs)2Sm(THF)2 catalyze the hydroaminatton/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organo-samarium complexes.",

author = "Gagn{\'e}, {Michel R.} and Nolan, {Steven P.} and Marks, {Tobin J.}",

year = "1990",

doi = "10.1021/om00156a005",

language = "English (US)",

volume = "9",

pages = "1716--1718",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Organolanthanide-centered hydroamination/cyclizatlon of aminoolefins. Expedient oxidative access to catalytic cycles

AU - Gagné, Michel R.

AU - Nolan, Steven P.

AU - Marks, Tobin J.

PY - 1990

Y1 - 1990

N2 - The readily accessible (Me5C5)2Sm and (Me5Cs)2Sm(THF)2 catalyze the hydroaminatton/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organo-samarium complexes.

AB - The readily accessible (Me5C5)2Sm and (Me5Cs)2Sm(THF)2 catalyze the hydroaminatton/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organo-samarium complexes.

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U2 - 10.1021/om00156a005

DO - 10.1021/om00156a005

M3 - Article

AN - SCOPUS:0000152417

SN - 0276-7333

VL - 9

SP - 1716

EP - 1718

JO - Organometallics

JF - Organometallics

IS - 6

ER -

Organolanthanide-centered hydroamination/cyclizatlon of aminoolefins. Expedient oxidative access to catalytic cycles

Abstract

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