Organolanthanide-centered hydroamination/cyclizatlon of aminoolefins. Expedient oxidative access to catalytic cycles

Michel R. Gagné, Steven P. Nolan, Tobin J. Marks*

*Corresponding author for this work

Research output: Contribution to journalArticle

159 Scopus citations

Abstract

The readily accessible (Me5C5)2Sm and (Me5Cs)2Sm(THF)2 catalyze the hydroaminatton/cyclization of a variety of aminoolefins. Mechanistic observations suggest that the active catalysts are trivalent organo-samarium complexes.

Original languageEnglish (US)
Pages (from-to)1716-1718
Number of pages3
JournalOrganometallics
Volume9
Issue number6
DOIs
StatePublished - Jan 1 1990

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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