Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

Moris S. Eisen; Tobin Jay Marks

doi:10.1021/om00060a006

Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

Moris S. Eisen, Tobin Jay Marks^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The adsorption of Th(η³-allyl)₄ on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D₂. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.

Original language	English (US)
Pages (from-to)	3939-3941
Number of pages	3
Journal	Organometallics
Volume	11
Issue number	12
DOIs	https://doi.org/10.1021/om00060a006
State	Published - Dec 1 1992

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1021/om00060a006

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title = "Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium",

abstract = "The adsorption of Th(η3-allyl)4 on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.",

author = "Eisen, {Moris S.} and Marks, {Tobin Jay}",

year = "1992",

month = dec,

day = "1",

doi = "10.1021/om00060a006",

language = "English (US)",

volume = "11",

pages = "3939--3941",

journal = "Organometallics",

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AU - Eisen, Moris S.

AU - Marks, Tobin Jay

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The adsorption of Th(η3-allyl)4 on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.

AB - The adsorption of Th(η3-allyl)4 on dehydroxylated alumina yields an active catalyst for the exchange of alkane and cycloalkane C-H bonds with D2. C-H reactivities fall in the order primary > secondary > tertiary and less sterically hindered > more sterlcally hindered.

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M3 - Article

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IS - 12

ER -

Organometallic Molecule-Inorganic Surface Coordination and Catalytic Chemistry. Facile and Selective Alkane Activation by Supported Tetraallylthorium

Abstract

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