Overcoming the achilles' heel of processing of polymer nanocomposites: Achieving well-dispersed polymer-graphite, polymer-carbon nanotube, polymer-carbon nanofiber, and polymer-graphene nanocomposites with major property enhancements by solid-state shear pulverization

John M Torkelson*, Philip J. Brunner, Neil Kane

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Polymer nanocomposites consisting of polypropylene (PP) and low levels of as-received graphite (ARG) or carbon nanotubes (CNT) were prepared via a continuous and industrially scalable process called solid-state shear pulverization (SSSP). This novel polymer processing technique exposes polymers to high shear and compressive forces near ambient temperature, which allows for fragmentaion and fusion steps in the solid-state. We found that SSSP processing leads to excellent exfoliation and dispersion of ARG and debundling and dispersion of CNT in the PP matrix. This excellent dispersion is accompanied by major property enhancements. For example, a 97.5/2.5 wt% PP/ARG nanocomposite made by SSSP exhibits a 100% increase in tensile modulus and a 50 % increase in tensile strength relative to neat PP while retaining most of the net PP elongation at break. Similar mechanical property enhancements are achieved with 99/1 wt% PP/carbon nanotube nanocomposites.

Original languageEnglish (US)
Title of host publicationTechnical Proceedings of the 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012
Pages556-559
Number of pages4
StatePublished - Aug 20 2012
EventNanotechnology 2012: Advanced Materials, CNTs, Particles, Films and Composites - 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012 - Santa Clara, CA, United States
Duration: Jun 18 2012Jun 21 2012

Other

OtherNanotechnology 2012: Advanced Materials, CNTs, Particles, Films and Composites - 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012
CountryUnited States
CitySanta Clara, CA
Period6/18/126/21/12

Fingerprint

Carbon Nanotubes
Carbon nanofibers
Graphite
Polypropylenes
Graphene
Carbon nanotubes
Nanocomposites
Polymers
Processing
Pulverization
Elongation
Tensile strength
Fusion reactions
Elastic moduli
Mechanical properties

Keywords

  • As-received graphite
  • Carbon nanotubes
  • Physical properties
  • Polyproplyene
  • Solid-state shear pulvierzation

ASJC Scopus subject areas

  • Ceramics and Composites
  • Surfaces, Coatings and Films

Cite this

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title = "Overcoming the achilles' heel of processing of polymer nanocomposites: Achieving well-dispersed polymer-graphite, polymer-carbon nanotube, polymer-carbon nanofiber, and polymer-graphene nanocomposites with major property enhancements by solid-state shear pulverization",
abstract = "Polymer nanocomposites consisting of polypropylene (PP) and low levels of as-received graphite (ARG) or carbon nanotubes (CNT) were prepared via a continuous and industrially scalable process called solid-state shear pulverization (SSSP). This novel polymer processing technique exposes polymers to high shear and compressive forces near ambient temperature, which allows for fragmentaion and fusion steps in the solid-state. We found that SSSP processing leads to excellent exfoliation and dispersion of ARG and debundling and dispersion of CNT in the PP matrix. This excellent dispersion is accompanied by major property enhancements. For example, a 97.5/2.5 wt{\%} PP/ARG nanocomposite made by SSSP exhibits a 100{\%} increase in tensile modulus and a 50 {\%} increase in tensile strength relative to neat PP while retaining most of the net PP elongation at break. Similar mechanical property enhancements are achieved with 99/1 wt{\%} PP/carbon nanotube nanocomposites.",
keywords = "As-received graphite, Carbon nanotubes, Physical properties, Polyproplyene, Solid-state shear pulvierzation",
author = "Torkelson, {John M} and Brunner, {Philip J.} and Neil Kane",
year = "2012",
month = "8",
day = "20",
language = "English (US)",
isbn = "9781466562745",
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Torkelson, JM, Brunner, PJ & Kane, N 2012, Overcoming the achilles' heel of processing of polymer nanocomposites: Achieving well-dispersed polymer-graphite, polymer-carbon nanotube, polymer-carbon nanofiber, and polymer-graphene nanocomposites with major property enhancements by solid-state shear pulverization. in Technical Proceedings of the 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012. pp. 556-559, Nanotechnology 2012: Advanced Materials, CNTs, Particles, Films and Composites - 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012, Santa Clara, CA, United States, 6/18/12.

Overcoming the achilles' heel of processing of polymer nanocomposites : Achieving well-dispersed polymer-graphite, polymer-carbon nanotube, polymer-carbon nanofiber, and polymer-graphene nanocomposites with major property enhancements by solid-state shear pulverization. / Torkelson, John M; Brunner, Philip J.; Kane, Neil.

Technical Proceedings of the 2012 NSTI Nanotechnology Conference and Expo, NSTI-Nanotech 2012. 2012. p. 556-559.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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N2 - Polymer nanocomposites consisting of polypropylene (PP) and low levels of as-received graphite (ARG) or carbon nanotubes (CNT) were prepared via a continuous and industrially scalable process called solid-state shear pulverization (SSSP). This novel polymer processing technique exposes polymers to high shear and compressive forces near ambient temperature, which allows for fragmentaion and fusion steps in the solid-state. We found that SSSP processing leads to excellent exfoliation and dispersion of ARG and debundling and dispersion of CNT in the PP matrix. This excellent dispersion is accompanied by major property enhancements. For example, a 97.5/2.5 wt% PP/ARG nanocomposite made by SSSP exhibits a 100% increase in tensile modulus and a 50 % increase in tensile strength relative to neat PP while retaining most of the net PP elongation at break. Similar mechanical property enhancements are achieved with 99/1 wt% PP/carbon nanotube nanocomposites.

AB - Polymer nanocomposites consisting of polypropylene (PP) and low levels of as-received graphite (ARG) or carbon nanotubes (CNT) were prepared via a continuous and industrially scalable process called solid-state shear pulverization (SSSP). This novel polymer processing technique exposes polymers to high shear and compressive forces near ambient temperature, which allows for fragmentaion and fusion steps in the solid-state. We found that SSSP processing leads to excellent exfoliation and dispersion of ARG and debundling and dispersion of CNT in the PP matrix. This excellent dispersion is accompanied by major property enhancements. For example, a 97.5/2.5 wt% PP/ARG nanocomposite made by SSSP exhibits a 100% increase in tensile modulus and a 50 % increase in tensile strength relative to neat PP while retaining most of the net PP elongation at break. Similar mechanical property enhancements are achieved with 99/1 wt% PP/carbon nanotube nanocomposites.

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