Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers

Naoko Ichiishi; Christian A. Malapit; Aukasz Woźniak; Melanie S. Sanford

doi:10.1021/acs.orglett.7b03305

Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers

Naoko Ichiishi, Christian A. Malapit, Aukasz Woźniak, Melanie S. Sanford^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

120 Scopus citations

Abstract

This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.

Original language	English (US)
Pages (from-to)	44-47
Number of pages	4
Journal	Organic Letters
Volume	20
Issue number	1
DOIs	https://doi.org/10.1021/acs.orglett.7b03305
State	Published - Jan 5 2018

Funding

We acknowledge financial support from NIH NIGMS (GM073836) as well as the Danish National Research Foundation (Carbon Dioxide Activation Center; CADIAC). We acknowledge financial support from NIH NIGMS (GM073836) as well as the Danish National Research Foundation (Carbon Dioxide Activation Center; CADIAC). Ł.W. thanks the UM-ICIQ Global Engagement Program for a fellowship.

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers",

abstract = "This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.",

author = "Naoko Ichiishi and Malapit, \{Christian A.\} and Aukasz Wo{\'z}niak and Sanford, \{Melanie S.\}",

note = "Funding Information: We acknowledge financial support from NIH NIGMS (GM073836) as well as the Danish National Research Foundation (Carbon Dioxide Activation Center; CADIAC). Funding Information: We acknowledge financial support from NIH NIGMS (GM073836) as well as the Danish National Research Foundation (Carbon Dioxide Activation Center; CADIAC). {\L}.W. thanks the UM-ICIQ Global Engagement Program for a fellowship. Publisher Copyright: {\textcopyright} 2017 American Chemical Society.",

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AU - Malapit, Christian A.

AU - Woźniak, Aukasz

AU - Sanford, Melanie S.

N1 - Funding Information: We acknowledge financial support from NIH NIGMS (GM073836) as well as the Danish National Research Foundation (Carbon Dioxide Activation Center; CADIAC). Funding Information: We acknowledge financial support from NIH NIGMS (GM073836) as well as the Danish National Research Foundation (Carbon Dioxide Activation Center; CADIAC). Ł.W. thanks the UM-ICIQ Global Engagement Program for a fellowship. Publisher Copyright: © 2017 American Chemical Society.

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N2 - This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.

AB - This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.

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Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers

Abstract

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