Phase diagram of charged dumbbells: A random phase approximation approach

Alexander Kudlay, Alexander V. Ermoshkin*, Monica Olvera de la Cruz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

6 Scopus citations

Abstract

The phase diagram of the charged hard dumbbell system (hard spheres of opposite unit charge fixed at contact) is obtained with the use of the random phase approximation (RPA). The effect of the impenetrability of charged spheres on charge-charge fluctuations is described by introduction of a modified electrostatic potential. The correlations of ions in a pair are included via a correlation function in the RPA. The coexistence curve is in good agreement with Monte Carlo simulations. The relevance of the theory to the restricted primitive model is discussed.

Original languageEnglish (US)
Pages (from-to)6
Number of pages1
JournalPhysical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics
Volume70
Issue number2
DOIs
StatePublished - 2004

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

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