Phosphine Gas Adsorption in a Series of Metal-Organic Frameworks

Mitchell H. Weston; William Morris; Paul W. Siu; William J. Hoover; David Cho; Rachelle K. Richardson; Omar K. Farha

doi:10.1021/acs.inorgchem.5b01055

Phosphine Gas Adsorption in a Series of Metal-Organic Frameworks

Mitchell H. Weston^*, William Morris, Paul W. Siu, William J. Hoover, David Cho, Rachelle K. Richardson, Omar K. Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

For the first time, phosphine adsorption has been evaluated in a series of metal-organic frameworks (MOFs). Open-metal coordination sites were found to significantly enhance the ability of MOFs to adsorb highly toxic phosphine gas, with the identity of the open-metal site also modulating the amount of gas adsorbed. The MOFs studied outperform activated carbon, a commonly used material to capture phosphine.

Original language	English (US)
Pages (from-to)	8162-8164
Number of pages	3
Journal	Inorganic chemistry
Volume	54
Issue number	17
DOIs	https://doi.org/10.1021/acs.inorgchem.5b01055
State	Published - Sep 8 2015

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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10.1021/acs.inorgchem.5b01055

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abstract = "For the first time, phosphine adsorption has been evaluated in a series of metal-organic frameworks (MOFs). Open-metal coordination sites were found to significantly enhance the ability of MOFs to adsorb highly toxic phosphine gas, with the identity of the open-metal site also modulating the amount of gas adsorbed. The MOFs studied outperform activated carbon, a commonly used material to capture phosphine.",

author = "Weston, {Mitchell H.} and William Morris and Siu, {Paul W.} and Hoover, {William J.} and David Cho and Richardson, {Rachelle K.} and Farha, {Omar K.}",

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AU - Siu, Paul W.

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AU - Cho, David

AU - Richardson, Rachelle K.

AU - Farha, Omar K.

PY - 2015/9/8

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AB - For the first time, phosphine adsorption has been evaluated in a series of metal-organic frameworks (MOFs). Open-metal coordination sites were found to significantly enhance the ability of MOFs to adsorb highly toxic phosphine gas, with the identity of the open-metal site also modulating the amount of gas adsorbed. The MOFs studied outperform activated carbon, a commonly used material to capture phosphine.

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Phosphine Gas Adsorption in a Series of Metal-Organic Frameworks

Abstract

ASJC Scopus subject areas

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