Photoacoustic overtone spectroscopy of M(CH3)4 compounds (M = C, Si, Ge, Sn)

Carlos Manzanares I*, N. L.S. Yamasaki, Eric Weitz, J. Thomas Knudtson

*Corresponding author for this work

Research output: Contribution to journalArticle

17 Scopus citations

Abstract

The gas-phase fundamental and overtone (υ = 1-7) spectra of the CH stretching modes of the series M(CH3)4 (M = C, Si, Ge, Sn) have been recorded using intracavity photoacoustic laser spectroscopy as well as standard infrared techniques. Absorption cross sections have been obtained for υ = 5 and 6 of the series. The change in frequency of the transitions and the mass-dependent changes in linewidth are interpreted in terms of a local mode description of vibrational overtones.

Original languageEnglish (US)
Pages (from-to)477-484
Number of pages8
JournalChemical Physics Letters
Volume117
Issue number5
DOIs
StatePublished - Jun 28 1985

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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