Abstract
Rates and yields of intramolecular exciplex formation and electrontransfer in polychromophoric arylamines may be modified dramatically by varying the nature of the aryl or the amino group as well as the nature and length of the chain between the two groups. In trichromophoric systems 1 containing one aryl and two amino groups, photoinduced electron transfer may be affected between the aryl group and one of the amino groups in fairly non-polar solvents.
Original language | English (US) |
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Pages (from-to) | 4669-4681 |
Number of pages | 13 |
Journal | Tetrahedron |
Volume | 45 |
Issue number | 15 |
DOIs | |
State | Published - 1989 |
Funding
AcknowledgementT. he authors from the University of Chicago wish to acknowledget he National Science Foundation for its generous support of thib‘work, and the work at the ArgonneN ational-Laboratory was supported by the.Diviiion of ChemicalS ciences, Office of Basic Rnergy Sciences, U.S. Departmento f Rnergy; under'dontract W-31-lOQ-Rng-38. The authors also wish to,thank Professor GrahamR . Pieming-for,his interest and assistance in the early phase of this work. ., .,
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry