Photoinitiated polymerization on metal surfaces

Frederick D. Lewis; Marshall J. Nepras; Hillary L. Hampsch

doi:10.1016/S0040-4020(01)90276-5

Photoinitiated polymerization on metal surfaces

Frederick D. Lewis^*, Marshall J. Nepras, Hillary L. Hampsch

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

Irradiation of acrolein vapors in the presence of films of nickel and other metals results in the formation of thin films of polyacrolein on the metal surface. The polyarcrolein film protects the metal surface from abrasion and corrosion. Polymer growth is more rapid on oxidized vs. unoxidized metal surfaces indicating a role for surface oxide sites in the polymerization process. Several other monomers investigated fail to form adhesive polymer films on metal films, but can be copolymerized with acrolein.

Original language	English (US)
Pages (from-to)	1635-1642
Number of pages	8
Journal	Tetrahedron
Volume	43
Issue number	7
DOIs	https://doi.org/10.1016/S0040-4020(01)90276-5
State	Published - 1987

ASJC Scopus subject areas

Biochemistry
Drug Discovery
Organic Chemistry

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10.1016/S0040-4020(01)90276-5

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@article{a75c0486d9c7404eaa2ae128787fc0d1,

title = "Photoinitiated polymerization on metal surfaces",

abstract = "Irradiation of acrolein vapors in the presence of films of nickel and other metals results in the formation of thin films of polyacrolein on the metal surface. The polyarcrolein film protects the metal surface from abrasion and corrosion. Polymer growth is more rapid on oxidized vs. unoxidized metal surfaces indicating a role for surface oxide sites in the polymerization process. Several other monomers investigated fail to form adhesive polymer films on metal films, but can be copolymerized with acrolein.",

author = "Lewis, {Frederick D.} and Nepras, {Marshall J.} and Hampsch, {Hillary L.}",

note = "Funding Information: Acknowledgment. We thank 3H for financial support and for providing the polymer-supported metal films, electron micrographs , and access to the vacuum chambor wed in this research. thanks are due to V. P. Thalacker and J. T. Simpson for their help in the planning an execution of this research and to W. Wendrickeon for his assistance with the experiments conducted at 3W. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.",

year = "1987",

doi = "10.1016/S0040-4020(01)90276-5",

language = "English (US)",

volume = "43",

pages = "1635--1642",

journal = "Tetrahedron",

issn = "0040-4020",

publisher = "Elsevier Ltd",

number = "7",

}

TY - JOUR

T1 - Photoinitiated polymerization on metal surfaces

AU - Lewis, Frederick D.

AU - Nepras, Marshall J.

AU - Hampsch, Hillary L.

N1 - Funding Information: Acknowledgment. We thank 3H for financial support and for providing the polymer-supported metal films, electron micrographs , and access to the vacuum chambor wed in this research. thanks are due to V. P. Thalacker and J. T. Simpson for their help in the planning an execution of this research and to W. Wendrickeon for his assistance with the experiments conducted at 3W. Copyright: Copyright 2014 Elsevier B.V., All rights reserved.

PY - 1987

Y1 - 1987

N2 - Irradiation of acrolein vapors in the presence of films of nickel and other metals results in the formation of thin films of polyacrolein on the metal surface. The polyarcrolein film protects the metal surface from abrasion and corrosion. Polymer growth is more rapid on oxidized vs. unoxidized metal surfaces indicating a role for surface oxide sites in the polymerization process. Several other monomers investigated fail to form adhesive polymer films on metal films, but can be copolymerized with acrolein.

AB - Irradiation of acrolein vapors in the presence of films of nickel and other metals results in the formation of thin films of polyacrolein on the metal surface. The polyarcrolein film protects the metal surface from abrasion and corrosion. Polymer growth is more rapid on oxidized vs. unoxidized metal surfaces indicating a role for surface oxide sites in the polymerization process. Several other monomers investigated fail to form adhesive polymer films on metal films, but can be copolymerized with acrolein.

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U2 - 10.1016/S0040-4020(01)90276-5

DO - 10.1016/S0040-4020(01)90276-5

M3 - Article

AN - SCOPUS:0000252117

SN - 0040-4020

VL - 43

SP - 1635

EP - 1642

JO - Tetrahedron

JF - Tetrahedron

IS - 7

ER -

Photoinitiated polymerization on metal surfaces

Abstract

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