Photolysis of intrasilicalite I2: Spectroscopy and dynamics

David B. Pedersen*, Eric Weitz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

3 Scopus citations


The photoexcitation of intrasilicalite in I2, which results in emission in the near-infrared, was discussed. A first order model, to describe the repulsive interaction between iodine and the zeolite cage that lead to caging, was developed. The analysis showed that an ion pair model of the excited state potential described the observed ultraviolet visible emission from this system.

Original languageEnglish (US)
Pages (from-to)9897-9906
Number of pages10
JournalJournal of Chemical Physics
Issue number22
StatePublished - Jun 8 2002

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry


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