Poised on the brink between a bistable complex and a compound

Jan Oskar Jeppesen*, Jan Becher, J. Fraser Stoddart

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

44 Scopus citations

Abstract

(figure presented) An enmeshed supramolecular complex, based on a semi-dumbbell-shaped component containing an asymmetrically substituted tetrathiafulvalene site and a 1,5-dioxynaphthalene site for encirclement by a cyclobis(paraquat-p-phenylene) ring component and with a "speed bump" in the form of an thiomethyl group situated between the two recognition sites, has been self-assembled. This complex is a mixture in acetone solution of two slowly interconverting [2]pseudorotaxanes, one of which is on the verge of being a [2]rotaxane at room temperature.

Original languageEnglish (US)
Pages (from-to)557-560
Number of pages4
JournalOrganic Letters
Volume4
Issue number4
DOIs
StatePublished - Feb 21 2002

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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