Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H2(pc)I compared with Those of Co(pc)I and Ni(pc)I: Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors

Dean E. Rende; Michael D. Heagy; Ronald L. Musselman; William B. Heuer; Kwangkyoung Liou; Julia A. Thompson; Brian M. Hoffman

doi:10.1021/ic00029a004

Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H₂(pc)I compared with Those of Co(pc)I and Ni(pc)I: Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors

Dean E. Rende, Michael D. Heagy, Ronald L. Musselman, William B. Heuer, Kwangkyoung Liou, Julia A. Thompson, Brian M. Hoffman^*

^*Corresponding author for this work

Chemistry

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1 Scopus citations

Abstract

Polarized single-crystal ultraviolet and visible specular reflectance spectra and Kramers-Kronig-transformed absorbance spectra of Cu(pc)I and H₂(pc)I allow clarification of metal-based charge-transfer transitions, especially when compared with earlier results on Ni(pc)I and Co(pc)I and recent calculations. Earlier out of plane assignments have been confirmed, and some modified assignments are proposed for in-plane transitions, including the well-known Soret transition.

Original language	English (US)
Pages (from-to)	352-358
Number of pages	7
Journal	Inorganic chemistry
Volume	31
Issue number	3
DOIs	https://doi.org/10.1021/ic00029a004
State	Published - Feb 1 1992

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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Rende, D. E., Heagy, M. D., Musselman, R. L., Heuer, W. B., Liou, K., Thompson, J. A., & Hoffman, B. M. (1992). Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H₂(pc)I compared with Those of Co(pc)I and Ni(pc)I: Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors. Inorganic chemistry, 31(3), 352-358. https://doi.org/10.1021/ic00029a004

@article{9a2df116545840a1b91bf9d9c0c3b3ac,

title = "Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H2(pc)I compared with Those of Co(pc)I and Ni(pc)I: Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors",

abstract = "Polarized single-crystal ultraviolet and visible specular reflectance spectra and Kramers-Kronig-transformed absorbance spectra of Cu(pc)I and H2(pc)I allow clarification of metal-based charge-transfer transitions, especially when compared with earlier results on Ni(pc)I and Co(pc)I and recent calculations. Earlier out of plane assignments have been confirmed, and some modified assignments are proposed for in-plane transitions, including the well-known Soret transition.",

author = "Rende, {Dean E.} and Heagy, {Michael D.} and Musselman, {Ronald L.} and Heuer, {William B.} and Kwangkyoung Liou and Thompson, {Julia A.} and Hoffman, {Brian M.}",

year = "1992",

month = feb,

day = "1",

doi = "10.1021/ic00029a004",

language = "English (US)",

volume = "31",

pages = "352--358",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "3",

}

Rende, DE, Heagy, MD, Musselman, RL, Heuer, WB, Liou, K, Thompson, JA & Hoffman, BM 1992, 'Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H₂(pc)I compared with Those of Co(pc)I and Ni(pc)I: Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors', Inorganic chemistry, vol. 31, no. 3, pp. 352-358. https://doi.org/10.1021/ic00029a004

Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H₂(pc)I compared with Those of Co(pc)I and Ni(pc)I: Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors. / Rende, Dean E.; Heagy, Michael D.; Musselman, Ronald L. et al.
In: Inorganic chemistry, Vol. 31, No. 3, 01.02.1992, p. 352-358.

Research output: Contribution to journal › Article › peer-review

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T1 - Polarized Specular Reflectance Spectra of the Partially Oxidized Phthalocyanines Cu(pc)I and H2(pc)I compared with Those of Co(pc)I and Ni(pc)I

T2 - Metal-Based Charge-Transfer Transitions in One-Dimensional Conductors

AU - Rende, Dean E.

AU - Heagy, Michael D.

AU - Musselman, Ronald L.

AU - Heuer, William B.

AU - Liou, Kwangkyoung

AU - Thompson, Julia A.

AU - Hoffman, Brian M.

PY - 1992/2/1

Y1 - 1992/2/1

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AB - Polarized single-crystal ultraviolet and visible specular reflectance spectra and Kramers-Kronig-transformed absorbance spectra of Cu(pc)I and H2(pc)I allow clarification of metal-based charge-transfer transitions, especially when compared with earlier results on Ni(pc)I and Co(pc)I and recent calculations. Earlier out of plane assignments have been confirmed, and some modified assignments are proposed for in-plane transitions, including the well-known Soret transition.

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