Polycatenation under thermodynamic control

Mark A. Olson; Ali Coskun; Lei Fang; Ashish N. Basuray; J. Fraser Stoddart

doi:10.1002/anie.201000421

Polycatenation under thermodynamic control

Mark A. Olson, Ali Coskun, Lei Fang, Ashish N. Basuray, J. Fraser Stoddart

Chemistry

Research output: Contribution to journal › Article › peer-review

32 Scopus citations

Abstract

Thermodynamic cat attacks! Iodide-catalyzed reversible nucleophilic attacks have been exploited to access side-chain polycatenanes under thermodynamic control. Multiple catenations occurring all along the polymer chain are entirely driven to completion by the intra- and intermolecular side-chain π-π stacking interactions of contiguous catenanes. (Figure Presented)

Original language	English (US)
Pages (from-to)	3151-3156
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	49
Issue number	18
DOIs	https://doi.org/10.1002/anie.201000421
State	Published - Apr 19 2010

Keywords

Catenanes
Polymers
Self-assembly
Template-directed synthesis
Thermodynamics

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.201000421

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abstract = "Thermodynamic cat attacks! Iodide-catalyzed reversible nucleophilic attacks have been exploited to access side-chain polycatenanes under thermodynamic control. Multiple catenations occurring all along the polymer chain are entirely driven to completion by the intra- and intermolecular side-chain π-π stacking interactions of contiguous catenanes. (Figure Presented)",

keywords = "Catenanes, Polymers, Self-assembly, Template-directed synthesis, Thermodynamics",

author = "Olson, {Mark A.} and Ali Coskun and Lei Fang and Basuray, {Ashish N.} and {Fraser Stoddart}, J.",

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AU - Coskun, Ali

AU - Fang, Lei

AU - Basuray, Ashish N.

AU - Fraser Stoddart, J.

PY - 2010/4/19

Y1 - 2010/4/19

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AB - Thermodynamic cat attacks! Iodide-catalyzed reversible nucleophilic attacks have been exploited to access side-chain polycatenanes under thermodynamic control. Multiple catenations occurring all along the polymer chain are entirely driven to completion by the intra- and intermolecular side-chain π-π stacking interactions of contiguous catenanes. (Figure Presented)

KW - Catenanes

KW - Polymers

KW - Self-assembly

KW - Template-directed synthesis

KW - Thermodynamics

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M3 - Article

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 18

ER -

Polycatenation under thermodynamic control

Abstract

Keywords

ASJC Scopus subject areas

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