Polychiral semiconducting carbon nanotube-fullerene solar cells

Maogang Gong; Tejas A. Shastry; Yu Xie; Marco Bernardi; Daniel Jasion; Kyle A. Luck; Tobin J. Marks; Jeffrey C. Grossman; Shenqiang Ren; Mark C. Hersam

doi:10.1021/nl5027452

Polychiral semiconducting carbon nanotube-fullerene solar cells

Maogang Gong, Tejas A. Shastry, Yu Xie, Marco Bernardi, Daniel Jasion, Kyle A. Luck, Tobin J. Marks, Jeffrey C. Grossman, Shenqiang Ren^*, Mark C. Hersam

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

102 Scopus citations

Abstract

Single-walled carbon nanotubes (SWCNTs) have highly desirable attributes for solution-processable thin-film photovoltaics (TFPVs), such as broadband absorption, high carrier mobility, and environmental stability. However, previous TFPVs incorporating photoactive SWCNTs have utilized architectures that have limited current, voltage, and ultimately power conversion efficiency (PCE). Here, we report a solar cell geometry that maximizes photocurrent using polychiral SWCNTs while retaining high photovoltage, leading to record-high efficiency SWCNT-fullerene solar cells with average NREL certified and champion PCEs of 2.5% and 3.1%, respectively. Moreover, these cells show significant absorption in the near-infrared portion of the solar spectrum that is currently inaccessible by many leading TFPV technologies.

Original language	English (US)
Pages (from-to)	5308-5314
Number of pages	7
Journal	Nano letters
Volume	14
Issue number	9
DOIs	https://doi.org/10.1021/nl5027452
State	Published - Sep 10 2014

Keywords

bulk heterojunction
carbon nanomaterials
nanowires
photovoltaic

ASJC Scopus subject areas

Bioengineering
Chemistry(all)
Materials Science(all)
Condensed Matter Physics
Mechanical Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1021/nl5027452

Cite this

@article{eab81773f5d8437f91604278a8dc8a11,

title = "Polychiral semiconducting carbon nanotube-fullerene solar cells",

abstract = "Single-walled carbon nanotubes (SWCNTs) have highly desirable attributes for solution-processable thin-film photovoltaics (TFPVs), such as broadband absorption, high carrier mobility, and environmental stability. However, previous TFPVs incorporating photoactive SWCNTs have utilized architectures that have limited current, voltage, and ultimately power conversion efficiency (PCE). Here, we report a solar cell geometry that maximizes photocurrent using polychiral SWCNTs while retaining high photovoltage, leading to record-high efficiency SWCNT-fullerene solar cells with average NREL certified and champion PCEs of 2.5% and 3.1%, respectively. Moreover, these cells show significant absorption in the near-infrared portion of the solar spectrum that is currently inaccessible by many leading TFPV technologies.",

keywords = "bulk heterojunction, carbon nanomaterials, nanowires, photovoltaic",

author = "Maogang Gong and Shastry, {Tejas A.} and Yu Xie and Marco Bernardi and Daniel Jasion and Luck, {Kyle A.} and Marks, {Tobin J.} and Grossman, {Jeffrey C.} and Shenqiang Ren and Hersam, {Mark C.}",

note = "Publisher Copyright: {\textcopyright} 2014 American Chemical Society.",

year = "2014",

month = sep,

day = "10",

doi = "10.1021/nl5027452",

language = "English (US)",

volume = "14",

pages = "5308--5314",

journal = "Nano Letters",

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publisher = "American Chemical Society",

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TY - JOUR

T1 - Polychiral semiconducting carbon nanotube-fullerene solar cells

AU - Gong, Maogang

AU - Shastry, Tejas A.

AU - Xie, Yu

AU - Bernardi, Marco

AU - Jasion, Daniel

AU - Luck, Kyle A.

AU - Marks, Tobin J.

AU - Grossman, Jeffrey C.

AU - Ren, Shenqiang

AU - Hersam, Mark C.

PY - 2014/9/10

Y1 - 2014/9/10

N2 - Single-walled carbon nanotubes (SWCNTs) have highly desirable attributes for solution-processable thin-film photovoltaics (TFPVs), such as broadband absorption, high carrier mobility, and environmental stability. However, previous TFPVs incorporating photoactive SWCNTs have utilized architectures that have limited current, voltage, and ultimately power conversion efficiency (PCE). Here, we report a solar cell geometry that maximizes photocurrent using polychiral SWCNTs while retaining high photovoltage, leading to record-high efficiency SWCNT-fullerene solar cells with average NREL certified and champion PCEs of 2.5% and 3.1%, respectively. Moreover, these cells show significant absorption in the near-infrared portion of the solar spectrum that is currently inaccessible by many leading TFPV technologies.

AB - Single-walled carbon nanotubes (SWCNTs) have highly desirable attributes for solution-processable thin-film photovoltaics (TFPVs), such as broadband absorption, high carrier mobility, and environmental stability. However, previous TFPVs incorporating photoactive SWCNTs have utilized architectures that have limited current, voltage, and ultimately power conversion efficiency (PCE). Here, we report a solar cell geometry that maximizes photocurrent using polychiral SWCNTs while retaining high photovoltage, leading to record-high efficiency SWCNT-fullerene solar cells with average NREL certified and champion PCEs of 2.5% and 3.1%, respectively. Moreover, these cells show significant absorption in the near-infrared portion of the solar spectrum that is currently inaccessible by many leading TFPV technologies.

KW - bulk heterojunction

KW - carbon nanomaterials

KW - nanowires

KW - photovoltaic

UR - http://www.scopus.com/inward/record.url?scp=84911420518&partnerID=8YFLogxK

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U2 - 10.1021/nl5027452

DO - 10.1021/nl5027452

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AN - SCOPUS:84911420518

SN - 1530-6984

VL - 14

SP - 5308

EP - 5314

JO - Nano Letters

JF - Nano Letters

IS - 9

ER -

Polychiral semiconducting carbon nanotube-fullerene solar cells

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

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