Polyelectrolytes in the presence of multivalent ions: Gelation versus segregation

A. V. Ermoshkin; M. Olvera De La Cruz

Polyelectrolytes in the presence of multivalent ions: Gelation versus segregation

A. V. Ermoshkin^*, M. Olvera De La Cruz

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The effect of long range electrostic interactions on gelation of polyelectrolyte chains induced by multivalent ions was determined. The approach taken could be used to describe gelation of charged chains bridged by other types of linkers through modification of K₂. It was also possible to account for variable weights of different types of cross-link functionalities m by allowing a K_m dependence.

Original language	English (US)
Article number	125504
Pages (from-to)	125504/1-125504/4
Journal	Physical review letters
Volume	90
Issue number	12
State	Published - Mar 28 2003

ASJC Scopus subject areas

Physics and Astronomy(all)

Cite this

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title = "Polyelectrolytes in the presence of multivalent ions: Gelation versus segregation",

abstract = "The effect of long range electrostic interactions on gelation of polyelectrolyte chains induced by multivalent ions was determined. The approach taken could be used to describe gelation of charged chains bridged by other types of linkers through modification of K2. It was also possible to account for variable weights of different types of cross-link functionalities m by allowing a Km dependence.",

author = "Ermoshkin, {A. V.} and {Olvera De La Cruz}, M.",

note = "Funding Information: We acknowledge the financial support of the NIH Grant No. GM62109-02, the NSF Grant No. EEC-0118025, and IBNAM, Northwestern University.",

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T1 - Polyelectrolytes in the presence of multivalent ions

T2 - Gelation versus segregation

AU - Ermoshkin, A. V.

AU - Olvera De La Cruz, M.

N1 - Funding Information: We acknowledge the financial support of the NIH Grant No. GM62109-02, the NSF Grant No. EEC-0118025, and IBNAM, Northwestern University.

PY - 2003/3/28

Y1 - 2003/3/28

N2 - The effect of long range electrostic interactions on gelation of polyelectrolyte chains induced by multivalent ions was determined. The approach taken could be used to describe gelation of charged chains bridged by other types of linkers through modification of K2. It was also possible to account for variable weights of different types of cross-link functionalities m by allowing a Km dependence.

AB - The effect of long range electrostic interactions on gelation of polyelectrolyte chains induced by multivalent ions was determined. The approach taken could be used to describe gelation of charged chains bridged by other types of linkers through modification of K2. It was also possible to account for variable weights of different types of cross-link functionalities m by allowing a Km dependence.

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ER -

Polyelectrolytes in the presence of multivalent ions: Gelation versus segregation

Abstract

ASJC Scopus subject areas

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