Polymorphism in Li2Mo4O13 revisited

Jared P. Smit, Peter C. Stair, Kenneth R. Poeppelmeier*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The structure of M-Li2Mo4O13 has been determined. M-Li2Mo4O13 crystallizes in the monoclinic and noncentrosymmetric space group P21 (No. 4) with cell parameters a = 8.2178(5) Å, b = 21.2814(13) Å, c = 8.5950(5) Å, β = 96.0880(10)°, Z = 2, and final residuals of RI = 0.0225 and wR2 = 0.0536. M-Li2Mo4O13 is one of three polymorphs and all three phases are Li-Mo cosubstituted V6O 13 homeotypes built on an identical oxygen-deficient cubic close-packed oxygen framework.

Original languageEnglish (US)
Pages (from-to)521-525
Number of pages5
JournalCrystal Growth and Design
Volume7
Issue number3
DOIs
StatePublished - Mar 2007

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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