Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

Amy L. Kopf; Paul A. Maggard; Charlotte L. Stern; Kenneth R. Poeppelmeier

doi:10.1107/S0108270105001605

Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ⁴N: N′-μ-dichromato-κ²O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ⁴N:N′-μ-dichromato- κ²O:O′]

Amy L. Kopf, Paul A. Maggard, Charlotte L. Stern, Kenneth R. Poeppelmeier^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr₂O₇)(C₁₀H₈N ₂)₂] and [Cu-(Cr₂O₇)(C ₁₀H₈N₂)₂], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr₂O₇]^2- and [MN ₄O₂]²⁺ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN₄O₂]²⁺ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

Original language	English (US)
Pages (from-to)	m165-m168
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	61
Issue number	4
DOIs	https://doi.org/10.1107/S0108270105001605
State	Published - Apr 2005

ASJC Scopus subject areas

General Biochemistry, Genetics and Molecular Biology

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10.1107/S0108270105001605

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@article{1a7a0a30fe7c447e8e07960d87cf506d,

title = "Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]",

abstract = "The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.",

author = "Kopf, {Amy L.} and Maggard, {Paul A.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R.}",

year = "2005",

month = apr,

doi = "10.1107/S0108270105001605",

language = "English (US)",

volume = "61",

pages = "m165--m168",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "4",

}

Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ⁴N: N′-μ-dichromato-κ²O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ⁴N:N′-μ-dichromato- κ²O:O′]. / Kopf, Amy L.; Maggard, Paul A.; Stern, Charlotte L. et al.
In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 61, No. 4, 04.2005, p. m165-m168.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N

T2 - N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

AU - Kopf, Amy L.

AU - Maggard, Paul A.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R.

PY - 2005/4

Y1 - 2005/4

N2 - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

AB - The novel title hybrid isomorphous organic-inorganic mixed-metal dichromates, [Ni(Cr2O7)(C10H8N 2)2] and [Cu-(Cr2O7)(C 10H8N2)2], have been synthesized. A non-centro-symmetric three-dimensional (4,6)-net is formed from a linear chain of vertex-linked [Cr2O7]2- and [MN 4O2]2+ (M = Ni and Cu) units, which in turn are linked by the planar bidentate 4,4′-bipyridine ligand through the four remaining vertices of the [MN4O2]2+ octahedra. There are two such three-dimensional nets that interpenetrate with inversion symmetry.

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U2 - 10.1107/S0108270105001605

DO - 10.1107/S0108270105001605

M3 - Article

C2 - 15805611

AN - SCOPUS:30744458818

SN - 0108-2701

VL - 61

SP - m165-m168

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 4

ER -

Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ⁴N: N′-μ-dichromato-κ²O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ⁴N:N′-μ-dichromato- κ²O:O′]

Abstract

ASJC Scopus subject areas

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CCDC 269007: Experimental Crystal Structure Determination

CCDC 269006: Experimental Crystal Structure Determination

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Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ4N: N′-μ-dichromato-κ2O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ4N:N′-μ-dichromato- κ2O:O′]

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 269007: Experimental Crystal Structure Determination

CCDC 269006: Experimental Crystal Structure Determination

Cite this

Poly[nickel(II)-di-μ-4,4′-bipyridyl-κ⁴N: N′-μ-dichromato-κ²O:O′] and poly[copper(II)-di- μ-4,4′-bipyridyl-κ⁴N:N′-μ-dichromato- κ²O:O′]