Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design

Alexander M. Spokoyny; Omar K. Farha; Karen L. Mulfort; Joseph T. Hupp; Chad A. Mirkin

doi:10.1016/j.ica.2010.08.007

Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design

Alexander M. Spokoyny, Omar K. Farha, Karen L. Mulfort, Joseph T. Hupp, Chad A. Mirkin

Chemistry

Research output: Contribution to journal › Article › peer-review

63 Scopus citations

Abstract

Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.

Original language	English (US)
Pages (from-to)	266-271
Number of pages	6
Journal	Inorganica Chimica Acta
Volume	364
Issue number	1
DOIs	https://doi.org/10.1016/j.ica.2010.08.007
State	Published - Dec 15 2010

Keywords

Carboranes
Coordination polymers
MOFs

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2010.08.007

Cite this

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title = "Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design",

abstract = "Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.",

keywords = "Carboranes, Coordination polymers, MOFs",

author = "Spokoyny, {Alexander M.} and Farha, {Omar K.} and Mulfort, {Karen L.} and Hupp, {Joseph T.} and Mirkin, {Chad A.}",

year = "2010",

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doi = "10.1016/j.ica.2010.08.007",

language = "English (US)",

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journal = "Inorganica Chimica Acta",

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T1 - Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design

AU - Spokoyny, Alexander M.

AU - Farha, Omar K.

AU - Mulfort, Karen L.

AU - Hupp, Joseph T.

AU - Mirkin, Chad A.

PY - 2010/12/15

Y1 - 2010/12/15

N2 - Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.

AB - Two new metal-organic framework (MOF) materials based on boron-rich cluster struts (p-carborane) are reported herein. Cu(I) catalyzed coupling chemistry was used to synthesize carboxylate-based ligands, which are substantially longer than the previously studied dicarboxylated p-carborane, leading to structures with greater porosity. Solvothermal syntheses involving these ligands and Zn salts were used to prepare two new Zn(II)-based MOFs with 2D and 3D open framework structures. Upon thermal activation, these MOFs retain the chemical identity of their frameworks, leading to highly porous materials.

KW - Carboranes

KW - Coordination polymers

KW - MOFs

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DO - 10.1016/j.ica.2010.08.007

M3 - Article

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SN - 0020-1693

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SP - 266

EP - 271

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1

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Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 773980: Experimental Crystal Structure Determination

CCDC 773979: Experimental Crystal Structure Determination

Cite this

Porosity tuning of carborane-based metal-organic frameworks (MOFs) via coordination chemistry and ligand design

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 773980: Experimental Crystal Structure Determination

CCDC 773979: Experimental Crystal Structure Determination

Cite this