Abstract
Reductive deselenation of selenodiazole-fused porphyrazines, followed by acylation of the resultant labile porphyrazinediamines, was used to prepare macrocycles bearing two Collins ligands, two oxamido residues, or two quinoline-2-carboxamido units. Peripheral coordination of copper(II) to the di-(quinoline-2-carboxamido)-porphyrazine gave a metal-linked face-to-face porphyrazine dimer array. Sequential derivatization of the two amino groups in the porphyrazinediamines was used to prepare mixed peripheral ligand systems including a dimetallic picolinamido-Schiff base porphyrazine. Such systems exhibit strong metal-metal spin coupling and are anticipated to be of value in the synthesis of novel electronic and magnetic materials.
Original language | English (US) |
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Pages (from-to) | 3686-3694 |
Number of pages | 9 |
Journal | Inorganic chemistry |
Volume | 45 |
Issue number | 9 |
DOIs | |
State | Published - May 1 2006 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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CCDC 294756: Experimental Crystal Structure Determination
Goslinski, T. (Creator), Zhong, C. (Creator), Fuchter, M. J. (Creator), Stern, C. L. (Creator), White, A. J. P. (Creator), Barrett, A. G. M. (Creator) & Hoffman, B. M. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9wq84, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9wq84&sid=DataCite
Dataset
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CCDC 294760: Experimental Crystal Structure Determination
Goslinski, T. (Creator), Zhong, C. (Creator), Fuchter, M. J. (Creator), Stern, C. L. (Creator), White, A. J. P. (Creator), Barrett, A. G. M. (Creator) & Hoffman, B. M. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9wqd8, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9wqd8&sid=DataCite
Dataset
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CCDC 294762: Experimental Crystal Structure Determination
Goslinski, T. (Creator), Zhong, C. (Creator), Fuchter, M. J. (Creator), Stern, C. L. (Creator), White, A. J. P. (Creator), Barrett, A. G. M. (Creator) & Hoffman, B. M. (Creator), Cambridge Crystallographic Data Centre, 2006
DOI: 10.5517/cc9wqgb, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc9wqgb&sid=DataCite
Dataset