Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics

Suzanne Bélanger; Joseph T. Hupp

doi:10.1002/(SICI)1521-3773(19990802)38:15<2222::AID-ANIE2222>3.0.CO;2-4

Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics

Suzanne Bélanger, Joseph T. Hupp^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

94 Scopus citations

Abstract

Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.

Original language	English (US)
Pages (from-to)	2222-2224
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	15
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990802)38:15<2222::AID-ANIE2222>3.0.CO;2-4
State	Published - Aug 2 1999

Keywords

Electrochemistry
Mesoporosity
Metallacycles
Nanostructures
Supramolecular chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/(SICI)1521-3773(19990802)38:15<2222::AID-ANIE2222>3.0.CO;2-4

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title = "Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics",

abstract = "Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.",

keywords = "Electrochemistry, Mesoporosity, Metallacycles, Nanostructures, Supramolecular chemistry",

author = "Suzanne B{\'e}langer and Hupp, {Joseph T.}",

year = "1999",

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T1 - Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics

AU - Bélanger, Suzanne

AU - Hupp, Joseph T.

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Y1 - 1999/8/2

N2 - Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.

AB - Mesoporous thin films based on neutral, porphyrin-bridged, tetrarhenium 'square' compounds (metallacycles) display permeability to molecules smaller than the dimensions of an individual square cavity, but blocking behavior toward larger species (see schematic representation). The characteristic permeant size cutoff can be systematically and predictably manipulated by decorating the walls of the porphyrin square with axially bound, mono-, bi-, and tetradentate ligands.

KW - Electrochemistry

KW - Mesoporosity

KW - Metallacycles

KW - Nanostructures

KW - Supramolecular chemistry

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M3 - Article

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JF - Angewandte Chemie - International Edition

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ER -

Porphyrin-based thin-film molecular materials with highly adjustable nanoscale porosity and permeability characteristics

Abstract

Keywords

ASJC Scopus subject areas

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