Positionally defined, binary semiconductor nanoparticles synthesized by scanning probe block copolymer lithography

Louise R. Giam; Shu He; Noah E. Horwitz; Daniel J. Eichelsdoerfer; Jinan Chai; Zijian Zheng; Dongwoo Kim; Wooyoung Shim; Chad A. Mirkin

doi:10.1021/nl204233r

Positionally defined, binary semiconductor nanoparticles synthesized by scanning probe block copolymer lithography

Louise R. Giam, Shu He, Noah E. Horwitz, Daniel J. Eichelsdoerfer, Jinan Chai, Zijian Zheng, Dongwoo Kim, Wooyoung Shim, Chad A. Mirkin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

We report the first method for synthesizing binary semiconductor materials by scanning probe block copolymer lithography (SPBCL) in desired locations on a surface. In this work, we utilize SPBCL to create polymer features containing a desired amount of Cd ²⁺, which is defined by the feature volume. When they are subsequently reacted in H ₂S in the vapor phase, a single CdS nanoparticle is formed in each block copolymer (BCP) feature. The CdS nanoparticles were shown to be both crystalline and luminescent. Importantly, the CdS nanoparticle sizes can be tuned since their diameters depend on the volume of the originally deposited BCP feature.

Original language	English (US)
Pages (from-to)	1022-1025
Number of pages	4
Journal	Nano letters
Volume	12
Issue number	2
DOIs	https://doi.org/10.1021/nl204233r
State	Published - Feb 8 2012

Keywords

Scanning probe
block copolymer
cadmium sulfide nanoparticles
lithography
semiconductor

ASJC Scopus subject areas

Bioengineering
Chemistry(all)
Materials Science(all)
Condensed Matter Physics
Mechanical Engineering

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10.1021/nl204233r

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title = "Positionally defined, binary semiconductor nanoparticles synthesized by scanning probe block copolymer lithography",

abstract = "We report the first method for synthesizing binary semiconductor materials by scanning probe block copolymer lithography (SPBCL) in desired locations on a surface. In this work, we utilize SPBCL to create polymer features containing a desired amount of Cd 2+, which is defined by the feature volume. When they are subsequently reacted in H 2S in the vapor phase, a single CdS nanoparticle is formed in each block copolymer (BCP) feature. The CdS nanoparticles were shown to be both crystalline and luminescent. Importantly, the CdS nanoparticle sizes can be tuned since their diameters depend on the volume of the originally deposited BCP feature.",

keywords = "Scanning probe, block copolymer, cadmium sulfide nanoparticles, lithography, semiconductor",

author = "Giam, {Louise R.} and Shu He and Horwitz, {Noah E.} and Eichelsdoerfer, {Daniel J.} and Jinan Chai and Zijian Zheng and Dongwoo Kim and Wooyoung Shim and Mirkin, {Chad A.}",

year = "2012",

month = feb,

day = "8",

doi = "10.1021/nl204233r",

language = "English (US)",

volume = "12",

pages = "1022--1025",

journal = "Nano Letters",

issn = "1530-6984",

publisher = "American Chemical Society",

number = "2",

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Positionally defined, binary semiconductor nanoparticles synthesized by scanning probe block copolymer lithography. / Giam, Louise R.; He, Shu; Horwitz, Noah E.; Eichelsdoerfer, Daniel J.; Chai, Jinan; Zheng, Zijian; Kim, Dongwoo; Shim, Wooyoung; Mirkin, Chad A.

In: Nano letters, Vol. 12, No. 2, 08.02.2012, p. 1022-1025.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Positionally defined, binary semiconductor nanoparticles synthesized by scanning probe block copolymer lithography

AU - Giam, Louise R.

AU - He, Shu

AU - Horwitz, Noah E.

AU - Eichelsdoerfer, Daniel J.

AU - Chai, Jinan

AU - Zheng, Zijian

AU - Kim, Dongwoo

AU - Shim, Wooyoung

AU - Mirkin, Chad A.

PY - 2012/2/8

Y1 - 2012/2/8

N2 - We report the first method for synthesizing binary semiconductor materials by scanning probe block copolymer lithography (SPBCL) in desired locations on a surface. In this work, we utilize SPBCL to create polymer features containing a desired amount of Cd 2+, which is defined by the feature volume. When they are subsequently reacted in H 2S in the vapor phase, a single CdS nanoparticle is formed in each block copolymer (BCP) feature. The CdS nanoparticles were shown to be both crystalline and luminescent. Importantly, the CdS nanoparticle sizes can be tuned since their diameters depend on the volume of the originally deposited BCP feature.

AB - We report the first method for synthesizing binary semiconductor materials by scanning probe block copolymer lithography (SPBCL) in desired locations on a surface. In this work, we utilize SPBCL to create polymer features containing a desired amount of Cd 2+, which is defined by the feature volume. When they are subsequently reacted in H 2S in the vapor phase, a single CdS nanoparticle is formed in each block copolymer (BCP) feature. The CdS nanoparticles were shown to be both crystalline and luminescent. Importantly, the CdS nanoparticle sizes can be tuned since their diameters depend on the volume of the originally deposited BCP feature.

KW - Scanning probe

KW - block copolymer

KW - cadmium sulfide nanoparticles

KW - lithography

KW - semiconductor

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JO - Nano Letters

JF - Nano Letters

SN - 1530-6984

IS - 2

ER -

Positionally defined, binary semiconductor nanoparticles synthesized by scanning probe block copolymer lithography

Abstract

Keywords

ASJC Scopus subject areas

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