Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So; M. Hassan Beyzavi; Rohan Sawhney; Osama Shekhah; Mohamed Eddaoudi; Salih S. Al-Juaid; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c4cc05727a

Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Monica C. So, M. Hassan Beyzavi, Rohan Sawhney, Osama Shekhah, Mohamed Eddaoudi, Salih S. Al-Juaid, Joseph T. Hupp^*, Omar K. Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

Original language	English (US)
Pages (from-to)	85-88
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	1
DOIs	https://doi.org/10.1039/c4cc05727a
State	Published - Jan 4 2015

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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author = "So, {Monica C.} and Beyzavi, {M. Hassan} and Rohan Sawhney and Osama Shekhah and Mohamed Eddaoudi and Al-Juaid, {Salih S.} and Hupp, {Joseph T.} and Farha, {Omar K.}",

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AU - So, Monica C.

AU - Beyzavi, M. Hassan

AU - Sawhney, Rohan

AU - Shekhah, Osama

AU - Eddaoudi, Mohamed

AU - Al-Juaid, Salih S.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

PY - 2015/1/4

Y1 - 2015/1/4

N2 - Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

AB - Herein, we demonstrate the robustness of layer-by-layer (LbL)-assembled, pillared-paddlewheel-type MOF films toward conversion to new or modified MOFs via solvent-assisted linker exchange (SALE) and post-assembly linker metalation. Further, we show that LbL synthesis can afford MOFs that have proven inaccessible through other de novo strategies.

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Post-assembly transformations of porphyrin-containing metal-organic framework (MOF) films fabricated via automated layer-by-layer coordination

Abstract

ASJC Scopus subject areas

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