Predicting and Designing Optical Properties of Inorganic Materials

James M. Rondinelli, Emmanouil Kioupakis

Research output: Contribution to journalArticlepeer-review

41 Scopus citations


Modern first-principles calculations based on density functional theory and related techniques enable the predictive modeling of the linear and nonlinear optical properties of materials without adjustable or empirical parameters. Today, atomistic calculations are an indispensable tool by which to understand the interrelationship between the underlying structure and the measured optical properties and are particularly suited for the design of new materials with desirable optical responses and performance. In this article, we discuss the first-principles design methodology, and we review recent results from the literature that exemplify the predictive power of the method for numerous inorganic materials and nanostructures. We also discuss topics of active research and future opportunities that will enable the wider adoption of atomistic simulation techniques for predictive materials design.

Original languageEnglish (US)
Pages (from-to)491-518
Number of pages28
JournalAnnual Review of Materials Research
StatePublished - Jul 1 2015


  • Absorption
  • Excitons
  • First-principles calculations
  • Optical materials
  • Second harmonic generation

ASJC Scopus subject areas

  • Materials Science(all)

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