Predictions of rotation-vibration effects in time-resolved photoelectron angular distributions

Stuart C. Althorpe, Tamar Seideman

Research output: Contribution to journalArticlepeer-review

26 Scopus citations

Abstract

Theoretical and numerical study shows that the measurement of time-resolved PADs yields a map of the time evolution of a rovibrational wave packet subject to rotation-vibration interactions. A convenient measure of the rotational composition of a wave packet is the expectation value of cos2 θ, θ being the polar Euler angle between an axis fixed in the molecule and an axis fixed in space. In the absence of rotation-vibration coupling 〈cos2 θ〉 is a smooth function of the pump-probe delay time, reflecting the slow rotational motions.

Original languageEnglish (US)
Pages (from-to)7901-7910
Number of pages10
JournalJournal of Chemical Physics
Volume113
Issue number18
DOIs
StatePublished - Nov 8 2000

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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