Probing radicals and reactive species in zeolites

David B. Pedersen*, Kurt Winkelmann, Eric Weitz

*Corresponding author for this work

Research output: Contribution to journalConference articlepeer-review

Abstract

Alkyl radicals can play an important role as intermediates in lean NOx chemistry. This type of chemistry is of relevance to the treatment of emissions from diesel engines. CN radicals have been identified as possible intermediates in a study of the catalytic reduction of propane or ethanol (under lean NOx conditions over a Cu-ZrO2 catalyst). However, monitoring radicals and/or other reactive species can involve specialized techniques. Diatomic iodine provides a model system in which the dynamics and interactions of intra-zeolite species can be probed, and where photodissociation leads to two atomic radicals. This work sheds light on how the nanoporous environment of the zeolite can affect photodissociation processes. The polar environment of the zeolite can stabilize states of the parent and photoproducts by interactions that are similar to those involving solvation.

Original languageEnglish (US)
Pages (from-to)366-367
Number of pages2
JournalACS National Meeting Book of Abstracts
Volume41
Issue number2
StatePublished - 2001
Event222nd ACS National Meeting - Chicago, IL, United States
Duration: Aug 26 2001Aug 30 2001

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Fingerprint Dive into the research topics of 'Probing radicals and reactive species in zeolites'. Together they form a unique fingerprint.

Cite this