TY - JOUR
T1 - Process-level modelling and optimization to evaluate metal-organic frameworks for post-combustion capture of CO2
AU - Yancy-Caballero, Daison
AU - Leperi, Karson T.
AU - Bucior, Benjamin J.
AU - Richardson, Rachelle K.
AU - Islamoglu, Timur
AU - Farha, Omar K.
AU - You, Fengqi
AU - Snurr, Randall Q.
N1 - Funding Information:
This work was financially supported by the National Science Foundation (CBET-1604890). This research was supported in part through the computational resources and staff contributions provided for the Quest high-performance computing facility (project allocation: p30624) at Northwestern University.
PY - 2020/8
Y1 - 2020/8
N2 - Many metal-organic framework (MOF) materials have been reported in the literature as promising for carbon capture applications based on isotherm data or simple adsorbent metrics. However, adsorption process conditions are often neglected in these evaluations. In this study, we performed process-level simulation and optimization of pressure swing adsorption processes on a set of promising MOFs reported in the literature for post-combustion carbon capture. Zeolite 13X was also included as a benchmark material. We examined the ability of the MOFs to achieve the Department of Energy goals of 90% CO2 purity and 90% CO2 recovery by employing process-level optimization using three different cycle configurations: a modified Skarstrom cycle, a five-step cycle, and a fractionated vacuum swing adsorption cycle. Then, we ranked the MOFs based on their economic performance by looking at the productivity and energy requirements for each cycle. We compared this ranking of the MOFs with the rankings provided by other metrics and found that the adsorbent rankings suggested by simplified metrics may differ significantly from the rankings predicted by detailed process optimization. The economic optimization analysis suggests that the best performing MOFs from those analyzed here are UTSA-16, Cu-TDPAT, Zn-MOF-74, Ti-MIL-91, and SIFSIX-3-Ni. Looking at the connection between process performance and material properties, we found that high CO2 working capacity, small pore size, and large difference between the heat of adsorption of CO2 and N2 promote CO2 capture ability based on this small data set. We synthesized one of the top performing MOFs, SIFSIX-3-Ni, and measured its CO2 and N2 adsorption isotherms. The measured isotherms allowed us to estimate the N2 heat of adsorption for SIFSIX-3-Ni, which was not previously available and was required for the process-level modelling.
AB - Many metal-organic framework (MOF) materials have been reported in the literature as promising for carbon capture applications based on isotherm data or simple adsorbent metrics. However, adsorption process conditions are often neglected in these evaluations. In this study, we performed process-level simulation and optimization of pressure swing adsorption processes on a set of promising MOFs reported in the literature for post-combustion carbon capture. Zeolite 13X was also included as a benchmark material. We examined the ability of the MOFs to achieve the Department of Energy goals of 90% CO2 purity and 90% CO2 recovery by employing process-level optimization using three different cycle configurations: a modified Skarstrom cycle, a five-step cycle, and a fractionated vacuum swing adsorption cycle. Then, we ranked the MOFs based on their economic performance by looking at the productivity and energy requirements for each cycle. We compared this ranking of the MOFs with the rankings provided by other metrics and found that the adsorbent rankings suggested by simplified metrics may differ significantly from the rankings predicted by detailed process optimization. The economic optimization analysis suggests that the best performing MOFs from those analyzed here are UTSA-16, Cu-TDPAT, Zn-MOF-74, Ti-MIL-91, and SIFSIX-3-Ni. Looking at the connection between process performance and material properties, we found that high CO2 working capacity, small pore size, and large difference between the heat of adsorption of CO2 and N2 promote CO2 capture ability based on this small data set. We synthesized one of the top performing MOFs, SIFSIX-3-Ni, and measured its CO2 and N2 adsorption isotherms. The measured isotherms allowed us to estimate the N2 heat of adsorption for SIFSIX-3-Ni, which was not previously available and was required for the process-level modelling.
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U2 - 10.1039/d0me00060d
DO - 10.1039/d0me00060d
M3 - Article
AN - SCOPUS:85092402673
VL - 5
SP - 1205
EP - 1218
JO - Molecular Systems Design and Engineering
JF - Molecular Systems Design and Engineering
SN - 2058-9689
IS - 7
ER -