Programming Colloidal Crystal Habit with Anisotropic Nanoparticle Building Blocks and DNA Bonds

Matthew N. O'Brien, Hai Xin Lin, Martin Girard, Monica Olvera De La Cruz, Chad A. Mirkin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

46 Scopus citations


Colloidal crystallization can be programmed using building blocks consisting of a nanoparticle core and DNA bonds to form materials with controlled crystal symmetry, lattice parameters, stoichiometry, and dimensionality. Despite this diversity of colloidal crystal structures, only spherical nanoparticles crystallized with BCC symmetry experimentally yield single crystals with well-defined crystal habits. Here, we use low-symmetry, anisotropic nanoparticles to overcome this limitation and to access single crystals with different equilibrium Wulff shapes: a cubic habit from cube-shaped nanoparticles, a rhombic dodecahedron habit from octahedron-shaped nanoparticles, and an octahedron habit from rhombic dodecahedron-shaped nanoparticles. The observation that one can control the microscopic shape of single crystals based upon control of particle building block and crystal symmetry has important fundamental and technological implications for this novel class of colloidal matter.

Original languageEnglish (US)
Pages (from-to)14562-14565
Number of pages4
JournalJournal of the American Chemical Society
Issue number44
StatePublished - Nov 9 2016

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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