Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex

Jungseok Heo; Chad A. Mirkin

doi:10.1002/anie.200503343

Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex

Jungseok Heo^*, Chad A. Mirkin

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

77 Scopus citations

Abstract

(Chemical Equation Presented) The weak-link approach is used to synthesize a four-coordinate Cu^I complex for the chiral recognition of mandelic acid. The chelation through 2,2′-bipyridine in a reaction that concomitantly breaks weak Cu-S links and opens the condensed structure into a 27-membered macrocycle switches on the complex so it acts as an enantioselective fluorescent receptor.

Original language	English (US)
Pages (from-to)	941-944
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	45
Issue number	6
DOIs	https://doi.org/10.1002/anie.200503343
State	Published - Jan 30 2006

Keywords

Allosterism
Coordination modes
Enantioselectivity
Fluorescence
Host-guest systems

ASJC Scopus subject areas

General Chemistry
Catalysis

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10.1002/anie.200503343

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abstract = "(Chemical Equation Presented) The weak-link approach is used to synthesize a four-coordinate CuI complex for the chiral recognition of mandelic acid. The chelation through 2,2′-bipyridine in a reaction that concomitantly breaks weak Cu-S links and opens the condensed structure into a 27-membered macrocycle switches on the complex so it acts as an enantioselective fluorescent receptor.",

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AU - Mirkin, Chad A.

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N2 - (Chemical Equation Presented) The weak-link approach is used to synthesize a four-coordinate CuI complex for the chiral recognition of mandelic acid. The chelation through 2,2′-bipyridine in a reaction that concomitantly breaks weak Cu-S links and opens the condensed structure into a 27-membered macrocycle switches on the complex so it acts as an enantioselective fluorescent receptor.

AB - (Chemical Equation Presented) The weak-link approach is used to synthesize a four-coordinate CuI complex for the chiral recognition of mandelic acid. The chelation through 2,2′-bipyridine in a reaction that concomitantly breaks weak Cu-S links and opens the condensed structure into a 27-membered macrocycle switches on the complex so it acts as an enantioselective fluorescent receptor.

KW - Allosterism

KW - Coordination modes

KW - Enantioselectivity

KW - Fluorescence

KW - Host-guest systems

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Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex

Abstract

Keywords

ASJC Scopus subject areas

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