Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

Junpei Kuwabara; Hyo Jae Yoon; Chad A. Mirkin; Antonio G. Dipasquale; Arnold L. Rheingold

doi:10.1039/b905150c

Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

Junpei Kuwabara, Hyo Jae Yoon, Chad A. Mirkin, Antonio G. Dipasquale, Arnold L. Rheingold

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.

Original language	English (US)
Pages (from-to)	4557-4559
Number of pages	3
Journal	Chemical Communications
Issue number	30
DOIs	https://doi.org/10.1039/b905150c
State	Published - 2009

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex",

abstract = "The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.",

author = "Junpei Kuwabara and Yoon, {Hyo Jae} and Mirkin, {Chad A.} and Dipasquale, {Antonio G.} and Rheingold, {Arnold L.}",

year = "2009",

doi = "10.1039/b905150c",

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pages = "4557--4559",

journal = "Chemical Communications",

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T1 - Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

AU - Kuwabara, Junpei

AU - Yoon, Hyo Jae

AU - Mirkin, Chad A.

AU - Dipasquale, Antonio G.

AU - Rheingold, Arnold L.

PY - 2009

Y1 - 2009

N2 - The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.

AB - The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.

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U2 - 10.1039/b905150c

DO - 10.1039/b905150c

M3 - Article

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EP - 4559

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 30

ER -

Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex

Abstract

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