Pseudocontact and Contact Shifts for 6-Aminobenzobicyclo[2.2.2]Octene and 2-Aminotriptycene. Sign of B 0

Leon M. Stock, Michael R. Wasielewski

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

The conformational preferences of radicals may be studied via their β-proton epr coupling constants. These constants are related to the average dihedral angle (θ) through eq 1 where pc π ; is the p orbital [formula omitted] spin density, and B 0 and B 2 are constants near 0 and 50 G, respectively. For anion radicals with structural constraints which require to be 90°, a β is very small, suggesting that |B 0 /B 2

Original languageEnglish (US)
Pages (from-to)2743-2744
Number of pages2
JournalJournal of the American Chemical Society
Volume95
Issue number8
DOIs
StatePublished - Apr 1 1973

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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