Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Casey J. Stephenson; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c5qi00010f

Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

Casey J. Stephenson, Joseph T. Hupp^*, Omar K. Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

Original language	English (US)
Pages (from-to)	448-452
Number of pages	5
Journal	Inorganic Chemistry Frontiers
Volume	2
Issue number	5
DOIs	https://doi.org/10.1039/c5qi00010f
State	Published - May 2015

ASJC Scopus subject areas

Inorganic Chemistry

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abstract = "Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.",

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AU - Hupp, Joseph T.

AU - Farha, Omar K.

N1 - Publisher Copyright: This journal is © the Partner Organisations 2015.

PY - 2015/5

Y1 - 2015/5

N2 - Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

AB - Pt@ZIF-8 composites with crystallite sizes of ca. 150 nm were synthesized. The composite was used as a catalyst for the regioselective hydrogenation of trans-1,3-hexadiene to 3-hexene. 1-Hexyne was hydrogenated to 1-hexene and hexane while 3-hexyne did not react. In all cases, the Pt@ZIF-8 composite had higher selectivity than Pt/C.

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Pt@ZIF-8 composite for the regioselective hydrogenation of terminal unsaturations in 1,3-dienes and alkynes

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