[pyH+]2[CdNb2(py)4O 2F10]2-

Paramasivan Halasyamani; Michael J. Willis; Kevin R. Heier; Charlotte L. Stern; Kenneth R. Poeppelmeier

doi:10.1107/S0108270196007573

[pyH⁺]₂[CdNb₂(py)₄O ₂F₁₀]^2-

Paramasivan Halasyamani, Michael J. Willis, Kevin R. Heier, Charlotte L. Stern, Kenneth R. Poeppelmeier^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A new Cd^II/Nb^v compound, bis(pyridinium) decafluoro-2κ⁵F,3κ⁵ F-di-μ-oxo-1:2κ²O;1:3κ ²O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C₅H₆N)₂[CdNb₂F₁₀O ₂(C₅H₅-N)₄], has been synthesized. The complex contains [CdNb₂(Py)₄F₁₀O₂]^2- anions (py is pyridine) linked via the pyridinium cation through N - H⁺⋯F hydrogen bonding. The anion is composed of two [NbF₅O_1/2]^- octahedra connected by O^2- to a central [Cd(py)₄O_2/2] octahedron.

Original language	English (US)
Pages (from-to)	2491-2493
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	10
DOIs	https://doi.org/10.1107/S0108270196007573
State	Published - Oct 15 1996

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

Access to Document

10.1107/S0108270196007573

Cite this

@article{39c212b3029f4b0787fc960e5336f709,

title = "[pyH+]2[CdNb2(py)4O 2F10]2-",

abstract = "A new CdII/Nbv compound, bis(pyridinium) decafluoro-2κ5F,3κ5 F-di-μ-oxo-1:2κ2O;1:3κ 2O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C5H6N)2[CdNb2F10O 2(C5H5-N)4], has been synthesized. The complex contains [CdNb2(Py)4F10O2]2- anions (py is pyridine) linked via the pyridinium cation through N - H+⋯F hydrogen bonding. The anion is composed of two [NbF5O1/2]- octahedra connected by O2- to a central [Cd(py)4O2/2] octahedron.",

author = "Paramasivan Halasyamani and Willis, {Michael J.} and Heier, {Kevin R.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R.}",

year = "1996",

month = oct,

day = "15",

doi = "10.1107/S0108270196007573",

language = "English (US)",

volume = "52",

pages = "2491--2493",

journal = "Acta Crystallographica Section C: Crystal Structure Communications",

issn = "0108-2701",

publisher = "International Union of Crystallography",

number = "10",

}

TY - JOUR

T1 - [pyH+]2[CdNb2(py)4O 2F10]2-

AU - Halasyamani, Paramasivan

AU - Willis, Michael J.

AU - Heier, Kevin R.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R.

PY - 1996/10/15

Y1 - 1996/10/15

N2 - A new CdII/Nbv compound, bis(pyridinium) decafluoro-2κ5F,3κ5 F-di-μ-oxo-1:2κ2O;1:3κ 2O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C5H6N)2[CdNb2F10O 2(C5H5-N)4], has been synthesized. The complex contains [CdNb2(Py)4F10O2]2- anions (py is pyridine) linked via the pyridinium cation through N - H+⋯F hydrogen bonding. The anion is composed of two [NbF5O1/2]- octahedra connected by O2- to a central [Cd(py)4O2/2] octahedron.

AB - A new CdII/Nbv compound, bis(pyridinium) decafluoro-2κ5F,3κ5 F-di-μ-oxo-1:2κ2O;1:3κ 2O-tetrakis(pyridine-N)-cadmiumdiniobium(2-), (C5H6N)2[CdNb2F10O 2(C5H5-N)4], has been synthesized. The complex contains [CdNb2(Py)4F10O2]2- anions (py is pyridine) linked via the pyridinium cation through N - H+⋯F hydrogen bonding. The anion is composed of two [NbF5O1/2]- octahedra connected by O2- to a central [Cd(py)4O2/2] octahedron.

UR - http://www.scopus.com/inward/record.url?scp=0030264912&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030264912&partnerID=8YFLogxK

U2 - 10.1107/S0108270196007573

DO - 10.1107/S0108270196007573

M3 - Article

AN - SCOPUS:0030264912

SN - 0108-2701

VL - 52

SP - 2491

EP - 2493

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 10

ER -

[pyH⁺]₂[CdNb₂(py)₄O ₂F₁₀]^2-

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 127975: Experimental Crystal Structure Determination

Cite this

[pyH+]2[CdNb2(py)4O 2F10]2-

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 127975: Experimental Crystal Structure Determination

Cite this

[pyH⁺]₂[CdNb₂(py)₄O ₂F₁₀]^2-