Quantifying the working stroke of tetrathiafulvalene-based electrochemically-driven linear motor-molecules

Sune Nygaard; Bo W. Laursen; Amar H. Flood; Camilla N. Hansen; Jan O. Jeppesen; J. Fraser Stoddart

doi:10.1039/b511575b

Quantifying the working stroke of tetrathiafulvalene-based electrochemically-driven linear motor-molecules

Sune Nygaard, Bo W. Laursen, Amar H. Flood, Camilla N. Hansen, Jan O. Jeppesen^*, J. Fraser Stoddart

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

62 Scopus citations

Abstract

A highly constrained [2]rotaxane, constructed in such a way that the tetracationic cyclobis(paraquat-p-phenylene) ring is restricted to reside on a monopyrrolotetrathiafulvalene unit, has been synthesised and characterised. This design allows the deslipping free energy barrier for the tetracationic ring in all three redox states of the rotaxane to be determined.

Original language	English (US)
Pages (from-to)	144-146
Number of pages	3
Journal	Chemical Communications
Issue number	2
DOIs	https://doi.org/10.1039/b511575b
State	Published - Apr 6 2006

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b511575b

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AU - Jeppesen, Jan O.

AU - Stoddart, J. Fraser

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Quantifying the working stroke of tetrathiafulvalene-based electrochemically-driven linear motor-molecules

Abstract

ASJC Scopus subject areas

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