Quantum and classical dynamics of HCl +/MgO(001) photodissociation

Hua Guo*, Tamar Seideman

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

The photodissociation dynamics of a molecular ion (HCl +) adsorbed on a single crystal insulator surface (MgO(001)) is investigated theoretically in a 2D dimensional model. Both quantum and classical methods have been used to study the dynamics. The structureless absorption spectra of the adsorbate are found to shift relative to their gas phase counterparts, due to the (de)stabilization of the excited states. The angular distributions of the desorbed hydrogen fragments are highly structured, in sharp contrast to the smooth, gaussian-like distributions obtained for the corresponding gas phase dissociation. A classical deflection function is introduced to illustrate the influence of rainbow scattering on the final hydrogen angular distributions.

Original languageEnglish (US)
Title of host publicationProceedings of SPIE - The International Society for Optical Engineering
Pages411-418
Number of pages8
Volume2547
StatePublished - Dec 1 1995
EventLaser Techniques for Surface Science II - San Diego, CA, USA
Duration: Jul 12 1995Jul 14 1995

Other

OtherLaser Techniques for Surface Science II
CitySan Diego, CA, USA
Period7/12/957/14/95

ASJC Scopus subject areas

  • Electrical and Electronic Engineering
  • Condensed Matter Physics

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