Randomly affected monomolecular reactions

Yuri A. Berlin*, Dmitri O. Drobnitsky, Vladimir V. Kuz'min

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

10 Scopus citations

Abstract

A general approach to the description of monomolecular reactions affected by random impacts has been developed on the basis of irreversible random transitions theory. Theoretical results derived allow us to account for concrete forms of stochastic affections and to evaluate statistical characteristics of reaction systems with monomolecular processes. Kinetic curves described in terms of the proposed theory provide information on certain properties of the random media. Such an approach gives a possibility to include both classical chemical kinetics and a polychromatic approximation as two limit cases. Exact solutions are given in two relevant cases in order to illustrate the applicability of the theory developed by the authors.

Original languageEnglish (US)
Pages (from-to)3163-3168
Number of pages6
JournalThe Journal of Chemical Physics
Volume100
Issue number4
DOIs
StatePublished - Jan 1 1994

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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