Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry

Ghada Ayoub; Bahar Karadeniz; Ashlee J. Howarth; Omar K. Farha; Ivica Lilović; Luzia S. Germann; Robert E. Dinnebier; Krunoslav Užarević; Tomislav Friščić

doi:10.1021/acs.chemmater.9b01068

Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry

Ghada Ayoub, Bahar Karadeniz, Ashlee J. Howarth, Omar K. Farha^*, Ivica Lilović, Luzia S. Germann, Robert E. Dinnebier, Krunoslav Užarević, Tomislav Friščić

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

57 Scopus citations

Abstract

Mechanochemistry enables targeted, rapid synthesis of bimetallic metal-organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the synthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechanochemistry into the target-oriented synthesis of mixed-metal MOFs.

Original language	English (US)
Pages (from-to)	5494-5501
Number of pages	8
Journal	Chemistry of Materials
Volume	31
Issue number	15
DOIs	https://doi.org/10.1021/acs.chemmater.9b01068
State	Published - Aug 13 2019

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/acs.chemmater.9b01068

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title = "Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry",

abstract = "Mechanochemistry enables targeted, rapid synthesis of bimetallic metal-organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the synthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechanochemistry into the target-oriented synthesis of mixed-metal MOFs.",

author = "Ghada Ayoub and Bahar Karadeniz and Howarth, {Ashlee J.} and Farha, {Omar K.} and Ivica Lilovi{\'c} and Germann, {Luzia S.} and Dinnebier, {Robert E.} and Krunoslav U{\v z}arevi{\'c} and Tomislav Fri{\v s}{\v c}i{\'c}",

note = "Funding Information: We acknowledge the support of NSERC Discovery Grant (RGPIN-2017-06467), E. W. R. Steacie Memorial Fellowship (SMFSU 507347-17), Croatian Science Foundation grant no. 4744, and Defense Threat Reduction Agency (HDTRA1-18-1-0003). Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

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doi = "10.1021/acs.chemmater.9b01068",

language = "English (US)",

volume = "31",

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AU - Ayoub, Ghada

AU - Karadeniz, Bahar

AU - Howarth, Ashlee J.

AU - Farha, Omar K.

AU - Lilović, Ivica

AU - Germann, Luzia S.

AU - Dinnebier, Robert E.

AU - Užarević, Krunoslav

AU - Friščić, Tomislav

N1 - Funding Information: We acknowledge the support of NSERC Discovery Grant (RGPIN-2017-06467), E. W. R. Steacie Memorial Fellowship (SMFSU 507347-17), Croatian Science Foundation grant no. 4744, and Defense Threat Reduction Agency (HDTRA1-18-1-0003). Publisher Copyright: © 2019 American Chemical Society.

PY - 2019/8/13

Y1 - 2019/8/13

N2 - Mechanochemistry enables targeted, rapid synthesis of bimetallic metal-organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the synthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechanochemistry into the target-oriented synthesis of mixed-metal MOFs.

AB - Mechanochemistry enables targeted, rapid synthesis of bimetallic metal-organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the synthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechanochemistry into the target-oriented synthesis of mixed-metal MOFs.

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Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry

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CCDC 1893479: Experimental Crystal Structure Determination

CCDC 1894933: Experimental Crystal Structure Determination

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Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry

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CCDC 1893479: Experimental Crystal Structure Determination

CCDC 1894933: Experimental Crystal Structure Determination

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