Rb3Ti3Te11

Fu Qiang Huang, James A. Ibers

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

Trirubidium trititanium undecatelluride, Rb3Ti3Te11, has been synthesized from the reaction of titanium, tellurium, and Rb2Te3 at 773 K. Its structure has been determined from single-crystal X-ray data. It is composed of one-dimensional [Ti3Te113-] chains built by face-sharing pentagonal TiTe7 bipyramids and distorted TiTe6 octahedra. These chains adopt hexagonal closest packing along the [101] direction. Rb atoms are located among these chains. The wide range of Te-Te interactions makes the assignment of formal oxidation states impossible. The compound is isostructural with Cs3Ti3Te11.

Original languageEnglish (US)
Pages (from-to)1059-1061
Number of pages3
JournalActa Crystallographica, Section C: Crystal Structure Communications
Volume56
Issue number9
DOIs
StatePublished - Sep 1 2000

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

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