Rb3Ti3Te11

Fu Qiang Huang; James A. Ibers

doi:10.1107/S0108270100009367

Rb₃Ti₃Te₁₁

Fu Qiang Huang, James A. Ibers

Chemistry

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Trirubidium trititanium undecatelluride, Rb₃Ti₃Te₁₁, has been synthesized from the reaction of titanium, tellurium, and Rb₂Te₃ at 773 K. Its structure has been determined from single-crystal X-ray data. It is composed of one-dimensional [Ti₃Te₁₁^3-] chains built by face-sharing pentagonal TiTe₇ bipyramids and distorted TiTe₆ octahedra. These chains adopt hexagonal closest packing along the [101] direction. Rb atoms are located among these chains. The wide range of Te-Te interactions makes the assignment of formal oxidation states impossible. The compound is isostructural with Cs₃Ti₃Te₁₁.

Original language	English (US)
Pages (from-to)	1059-1061
Number of pages	3
Journal	Acta Crystallographica, Section C: Crystal Structure Communications
Volume	56
Issue number	9
DOIs	https://doi.org/10.1107/S0108270100009367
State	Published - Sep 1 2000

ASJC Scopus subject areas

Biochemistry, Genetics and Molecular Biology(all)

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@article{18141076c4cf47e8adda482a012dd481,

title = "Rb3Ti3Te11",

abstract = "Trirubidium trititanium undecatelluride, Rb3Ti3Te11, has been synthesized from the reaction of titanium, tellurium, and Rb2Te3 at 773 K. Its structure has been determined from single-crystal X-ray data. It is composed of one-dimensional [Ti3Te113-] chains built by face-sharing pentagonal TiTe7 bipyramids and distorted TiTe6 octahedra. These chains adopt hexagonal closest packing along the [101] direction. Rb atoms are located among these chains. The wide range of Te-Te interactions makes the assignment of formal oxidation states impossible. The compound is isostructural with Cs3Ti3Te11.",

author = "Huang, {Fu Qiang} and Ibers, {James A.}",

year = "2000",

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day = "1",

doi = "10.1107/S0108270100009367",

language = "English (US)",

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journal = "Acta Crystallographica Section C: Crystal Structure Communications",

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publisher = "International Union of Crystallography",

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T1 - Rb3Ti3Te11

AU - Huang, Fu Qiang

AU - Ibers, James A.

PY - 2000/9/1

Y1 - 2000/9/1

N2 - Trirubidium trititanium undecatelluride, Rb3Ti3Te11, has been synthesized from the reaction of titanium, tellurium, and Rb2Te3 at 773 K. Its structure has been determined from single-crystal X-ray data. It is composed of one-dimensional [Ti3Te113-] chains built by face-sharing pentagonal TiTe7 bipyramids and distorted TiTe6 octahedra. These chains adopt hexagonal closest packing along the [101] direction. Rb atoms are located among these chains. The wide range of Te-Te interactions makes the assignment of formal oxidation states impossible. The compound is isostructural with Cs3Ti3Te11.

AB - Trirubidium trititanium undecatelluride, Rb3Ti3Te11, has been synthesized from the reaction of titanium, tellurium, and Rb2Te3 at 773 K. Its structure has been determined from single-crystal X-ray data. It is composed of one-dimensional [Ti3Te113-] chains built by face-sharing pentagonal TiTe7 bipyramids and distorted TiTe6 octahedra. These chains adopt hexagonal closest packing along the [101] direction. Rb atoms are located among these chains. The wide range of Te-Te interactions makes the assignment of formal oxidation states impossible. The compound is isostructural with Cs3Ti3Te11.

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