Reactions of Carbonyl Sulfide and Carbon Disulfide with Iron and Ruthenium Complexes. Synthesis and Reactivity of Dicarbonyl(η2-carbonyl sulfide)bis(triphenylphosphine) ruthenium (0)

Thomas R. Gaffney, James A. Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticle

46 Scopus citations

Abstract

The reaction of Fe(CO)2(PPh3)3 with COS in toluene results in the formation of Fe(CO)3(PPh3)2 and SPPh3. When liquefied COS is used as the solvent, Fe(S2CO)(CO)2(PPh3)2 is also formed. The analogous ruthenium complex, Ru(CO)2(PPh3)3, reacts with COS to afford Ru(CO)22-COS)(PPh3)2. This COS complex reacts with additional COS to give Ru(S2CO)(CO)2(PPh3)2 and with PPh3 to give Ru(CO)3(PPh3)2 and SPPh3.

Original languageEnglish (US)
Pages (from-to)2851-2853
Number of pages3
JournalInorganic chemistry
Volume21
Issue number7
DOIs
StatePublished - Jan 1 1982

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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