Reactions of diazoalkanes with unsaturated CF3-ketones

V. G. Nenajdenko; A. V. Statsuk; E. S. Balenkova

doi:10.1023/A:1025189930975

Reactions of diazoalkanes with unsaturated CF₃-ketones

V. G. Nenajdenko^*, A. V. Statsuk, E. S. Balenkova

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The cycloaddition reactions of various diazoalkanes with unsaturated trifluoromethyl-containing ketones have been investigated. The reactions proceed regiospecifically and stereoselectively to the formation of trifluoroacetyl derivatives of 1H-pyrazolines.

Original language	English (US)
Pages (from-to)	598-603
Number of pages	6
Journal	Chemistry of Heterocyclic Compounds
Volume	39
Issue number	5
DOIs	https://doi.org/10.1023/A:1025189930975
State	Published - May 2003

Funding

The investigation described in this publication was carried out with the partial support of the Russian Fund for Fundamental Investigations (grant No. 00-03-32760a).

Keywords

CF-heterocycles
Cycloaddition
Diazoalkanes
Dipolarophiles
Dipoles

ASJC Scopus subject areas

Organic Chemistry

Access to Document

10.1023/A:1025189930975

Cite this

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title = "Reactions of diazoalkanes with unsaturated CF3-ketones",

abstract = "The cycloaddition reactions of various diazoalkanes with unsaturated trifluoromethyl-containing ketones have been investigated. The reactions proceed regiospecifically and stereoselectively to the formation of trifluoroacetyl derivatives of 1H-pyrazolines.",

keywords = "CF-heterocycles, Cycloaddition, Diazoalkanes, Dipolarophiles, Dipoles",

author = "Nenajdenko, {V. G.} and Statsuk, {A. V.} and Balenkova, {E. S.}",

note = "Funding Information: The investigation described in this publication was carried out with the partial support of the Russian Fund for Fundamental Investigations (grant No. 00-03-32760a).",

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T1 - Reactions of diazoalkanes with unsaturated CF3-ketones

AU - Nenajdenko, V. G.

AU - Statsuk, A. V.

AU - Balenkova, E. S.

N1 - Funding Information: The investigation described in this publication was carried out with the partial support of the Russian Fund for Fundamental Investigations (grant No. 00-03-32760a).

PY - 2003/5

Y1 - 2003/5

N2 - The cycloaddition reactions of various diazoalkanes with unsaturated trifluoromethyl-containing ketones have been investigated. The reactions proceed regiospecifically and stereoselectively to the formation of trifluoroacetyl derivatives of 1H-pyrazolines.

AB - The cycloaddition reactions of various diazoalkanes with unsaturated trifluoromethyl-containing ketones have been investigated. The reactions proceed regiospecifically and stereoselectively to the formation of trifluoroacetyl derivatives of 1H-pyrazolines.

KW - CF-heterocycles

KW - Cycloaddition

KW - Diazoalkanes

KW - Dipolarophiles

KW - Dipoles

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