Reactions of transition-metal cations with [Re6Te 8(CN)6]4- (see abstract)

Konstantin A. Brylev; Perumal Sekar; Nikolai G. Naumov; Vladimir E. Fedorov; James A. Ibers

doi:10.1016/j.ica.2003.06.014

Reactions of transition-metal cations with [Re₆Te ₈(CN)₆]^4- (see abstract)

Konstantin A. Brylev, Perumal Sekar, Nikolai G. Naumov, Vladimir E. Fedorov, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

15 Scopus citations

Abstract

The compounds [Zn(NH₃)₄]₂[Re ₆Te₈(CN)₆](1), [{Co(NH₃) ₅}₂Re₆Te₈(CN)₆] ·4H₂O (2), and [{Ni(NH₃)₅} ₂Re₆Te₈(CN)₆]·4H ₂O (3) have been synthesized by the diffusion of an ammonia solution of Cs₄[Re₆Te₈(CN)₆]·2H ₂O into a glycerol solution of ZnCl₂ (for 1), CoCl ₂·6H₂O (for 2), or NiCl₂·6H ₂O (for 3). Compound 1 crystallizes in the trigonal space group P3̄1m with one formula in a unit cell of dimensions a=10.3776(8) Å, c=10.4322(11) Å, and V=972.97(15) Å³ (T=153 K). Compounds 2 and 3 crystallize with four formula units in space group C2/c with cells of dimensions a=20.808(2) Å, b=22.027(3) Å, c=10.3708(11) Å, β=110.958(2)°, and V=4438.9(8) Å³ (T=153 K) (for 2); a=20.7617(15) Å, b=22.0521(16) Å, c=10.3526(8) Å, β=110.692(1)°, and V=4434.1(6) Å³ (T=153 K) (for 3). Compound 1 is ionic whereas compounds 2 and 3, which are isostructural, are molecular comprising two M(NH₃)₅ groups (M=Co, Ni) bonded in a trans fashion to the Re₆Te₈(CN)₆ cluster through M-N(cyanide) bonds.

Original language	English (US)
Pages (from-to)	728-732
Number of pages	5
Journal	Inorganica Chimica Acta
Volume	357
Issue number	3
DOIs	https://doi.org/10.1016/j.ica.2003.06.014
State	Published - Feb 20 2004

Funding

This research was supported by the U.S. National Science Foundation, Grant No. CHE-9819385.

Keywords

Rhenium clusters
Transition-metal ammines
X-ray structures

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

Access to Document

10.1016/j.ica.2003.06.014

Cite this

@article{a8c3f02c58804ae8ab3d017959ca52ca,

title = "Reactions of transition-metal cations with [Re6Te 8(CN)6]4- (see abstract)",

abstract = "The compounds [Zn(NH3)4]2[Re 6Te8(CN)6](1), [{Co(NH3) 5}2Re6Te8(CN)6] ·4H2O (2), and [{Ni(NH3)5} 2Re6Te8(CN)6]·4H 2O (3) have been synthesized by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of ZnCl2 (for 1), CoCl 2·6H2O (for 2), or NiCl2·6H 2O (for 3). Compound 1 crystallizes in the trigonal space group P{\=3}1m with one formula in a unit cell of dimensions a=10.3776(8) {\AA}, c=10.4322(11) {\AA}, and V=972.97(15) {\AA}3 (T=153 K). Compounds 2 and 3 crystallize with four formula units in space group C2/c with cells of dimensions a=20.808(2) {\AA}, b=22.027(3) {\AA}, c=10.3708(11) {\AA}, β=110.958(2)°, and V=4438.9(8) {\AA}3 (T=153 K) (for 2); a=20.7617(15) {\AA}, b=22.0521(16) {\AA}, c=10.3526(8) {\AA}, β=110.692(1)°, and V=4434.1(6) {\AA}3 (T=153 K) (for 3). Compound 1 is ionic whereas compounds 2 and 3, which are isostructural, are molecular comprising two M(NH3)5 groups (M=Co, Ni) bonded in a trans fashion to the Re6Te8(CN)6 cluster through M-N(cyanide) bonds.",

keywords = "Rhenium clusters, Transition-metal ammines, X-ray structures",

author = "Brylev, {Konstantin A.} and Perumal Sekar and Naumov, {Nikolai G.} and Fedorov, {Vladimir E.} and Ibers, {James A.}",

note = "Funding Information: This research was supported by the U.S. National Science Foundation, Grant No. CHE-9819385. ",

year = "2004",

month = feb,

day = "20",

doi = "10.1016/j.ica.2003.06.014",

language = "English (US)",

volume = "357",

pages = "728--732",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Reactions of transition-metal cations with [Re6Te 8(CN)6]4- (see abstract)

AU - Brylev, Konstantin A.

AU - Sekar, Perumal

AU - Naumov, Nikolai G.

AU - Fedorov, Vladimir E.

AU - Ibers, James A.

N1 - Funding Information: This research was supported by the U.S. National Science Foundation, Grant No. CHE-9819385.

PY - 2004/2/20

Y1 - 2004/2/20

N2 - The compounds [Zn(NH3)4]2[Re 6Te8(CN)6](1), [{Co(NH3) 5}2Re6Te8(CN)6] ·4H2O (2), and [{Ni(NH3)5} 2Re6Te8(CN)6]·4H 2O (3) have been synthesized by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of ZnCl2 (for 1), CoCl 2·6H2O (for 2), or NiCl2·6H 2O (for 3). Compound 1 crystallizes in the trigonal space group P3̄1m with one formula in a unit cell of dimensions a=10.3776(8) Å, c=10.4322(11) Å, and V=972.97(15) Å3 (T=153 K). Compounds 2 and 3 crystallize with four formula units in space group C2/c with cells of dimensions a=20.808(2) Å, b=22.027(3) Å, c=10.3708(11) Å, β=110.958(2)°, and V=4438.9(8) Å3 (T=153 K) (for 2); a=20.7617(15) Å, b=22.0521(16) Å, c=10.3526(8) Å, β=110.692(1)°, and V=4434.1(6) Å3 (T=153 K) (for 3). Compound 1 is ionic whereas compounds 2 and 3, which are isostructural, are molecular comprising two M(NH3)5 groups (M=Co, Ni) bonded in a trans fashion to the Re6Te8(CN)6 cluster through M-N(cyanide) bonds.

AB - The compounds [Zn(NH3)4]2[Re 6Te8(CN)6](1), [{Co(NH3) 5}2Re6Te8(CN)6] ·4H2O (2), and [{Ni(NH3)5} 2Re6Te8(CN)6]·4H 2O (3) have been synthesized by the diffusion of an ammonia solution of Cs4[Re6Te8(CN)6]·2H 2O into a glycerol solution of ZnCl2 (for 1), CoCl 2·6H2O (for 2), or NiCl2·6H 2O (for 3). Compound 1 crystallizes in the trigonal space group P3̄1m with one formula in a unit cell of dimensions a=10.3776(8) Å, c=10.4322(11) Å, and V=972.97(15) Å3 (T=153 K). Compounds 2 and 3 crystallize with four formula units in space group C2/c with cells of dimensions a=20.808(2) Å, b=22.027(3) Å, c=10.3708(11) Å, β=110.958(2)°, and V=4438.9(8) Å3 (T=153 K) (for 2); a=20.7617(15) Å, b=22.0521(16) Å, c=10.3526(8) Å, β=110.692(1)°, and V=4434.1(6) Å3 (T=153 K) (for 3). Compound 1 is ionic whereas compounds 2 and 3, which are isostructural, are molecular comprising two M(NH3)5 groups (M=Co, Ni) bonded in a trans fashion to the Re6Te8(CN)6 cluster through M-N(cyanide) bonds.

KW - Rhenium clusters

KW - Transition-metal ammines

KW - X-ray structures

UR - http://www.scopus.com/inward/record.url?scp=1242343778&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=1242343778&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2003.06.014

DO - 10.1016/j.ica.2003.06.014

M3 - Article

AN - SCOPUS:1242343778

SN - 0020-1693

VL - 357

SP - 728

EP - 732

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 3

ER -

Reactions of transition-metal cations with [Re₆Te ₈(CN)₆]^4- (see abstract)

Abstract

Funding

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 1509745: Experimental Crystal Structure Determination

CCDC 1509747: Experimental Crystal Structure Determination

CCDC 1509746: Experimental Crystal Structure Determination

Cite this

Reactions of transition-metal cations with [Re6Te 8(CN)6]4- (see abstract)

Abstract

Funding

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 1509745: Experimental Crystal Structure Determination

CCDC 1509747: Experimental Crystal Structure Determination

CCDC 1509746: Experimental Crystal Structure Determination

Cite this

Reactions of transition-metal cations with [Re₆Te ₈(CN)₆]^4- (see abstract)