Reactive flux syntheses at low and high temperatures

J. A. Cody; M. F. Mansuetto; S. Chien; J. A. Ibers

doi:10.4028/www.scientific.net/msf.152-153.35

Reactive flux syntheses at low and high temperatures

J. A. Cody^*, M. F. Mansuetto, S. Chien, J. A. Ibers

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Conference article › peer-review

22 Scopus citations

Abstract

This paper reviews the reactive flux method for the synthesis of ternary and quaternary metal polychalcogenides, starting with the early synthesis of K₄Ti₃S₁₄ and Na₂Ti₂Se₈. It is shown that a variety of interesting solid-state metal chalcogenides, many of which show low dimensionality, may be synthesized over a range of temperatures. Compounds discussed include K₄Hf₃Te₁₇ and Cs₄Zr₃Te₁₆, the series Cu₃NbSe₄, KCu₂NbSe₄, K₂CuNbSe₄, and K₃NbSe₄, KCuMQ₃ and NaCuMQ₃ (M = Ti, Zr, Hf; Q = S, Se, Te), Cs_0.68CuTiTe₄, and CsTiUTe₅. The unusual structural features of some of these newly synthesized compounds are discussed.

Original language	English (US)
Pages (from-to)	35-42
Number of pages	8
Journal	Materials Science Forum
Volume	152-5
DOIs	https://doi.org/10.4028/www.scientific.net/msf.152-153.35
State	Published - 1994
Event	Proceedings of the International Symposium on Soft Chemistry Routes to New Materials - Nantes, Fr Duration: Sep 6 1993 → Sep 10 1993

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering

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@article{d34fc8726742457fbdbf51ac64623534,

title = "Reactive flux syntheses at low and high temperatures",

abstract = "This paper reviews the reactive flux method for the synthesis of ternary and quaternary metal polychalcogenides, starting with the early synthesis of K4Ti3S14 and Na2Ti2Se8. It is shown that a variety of interesting solid-state metal chalcogenides, many of which show low dimensionality, may be synthesized over a range of temperatures. Compounds discussed include K4Hf3Te17 and Cs4Zr3Te16, the series Cu3NbSe4, KCu2NbSe4, K2CuNbSe4, and K3NbSe4, KCuMQ3 and NaCuMQ3 (M = Ti, Zr, Hf; Q = S, Se, Te), Cs0.68CuTiTe4, and CsTiUTe5. The unusual structural features of some of these newly synthesized compounds are discussed.",

author = "Cody, {J. A.} and Mansuetto, {M. F.} and S. Chien and Ibers, {J. A.}",

note = "Copyright: Copyright 2020 Elsevier B.V., All rights reserved.; Proceedings of the International Symposium on Soft Chemistry Routes to New Materials ; Conference date: 06-09-1993 Through 10-09-1993",

year = "1994",

doi = "10.4028/www.scientific.net/msf.152-153.35",

language = "English (US)",

volume = "152-5",

pages = "35--42",

journal = "Materials Science Forum",

issn = "0255-5476",

publisher = "Trans Tech Publications",

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TY - JOUR

T1 - Reactive flux syntheses at low and high temperatures

AU - Cody, J. A.

AU - Mansuetto, M. F.

AU - Chien, S.

AU - Ibers, J. A.

PY - 1994

Y1 - 1994

N2 - This paper reviews the reactive flux method for the synthesis of ternary and quaternary metal polychalcogenides, starting with the early synthesis of K4Ti3S14 and Na2Ti2Se8. It is shown that a variety of interesting solid-state metal chalcogenides, many of which show low dimensionality, may be synthesized over a range of temperatures. Compounds discussed include K4Hf3Te17 and Cs4Zr3Te16, the series Cu3NbSe4, KCu2NbSe4, K2CuNbSe4, and K3NbSe4, KCuMQ3 and NaCuMQ3 (M = Ti, Zr, Hf; Q = S, Se, Te), Cs0.68CuTiTe4, and CsTiUTe5. The unusual structural features of some of these newly synthesized compounds are discussed.

AB - This paper reviews the reactive flux method for the synthesis of ternary and quaternary metal polychalcogenides, starting with the early synthesis of K4Ti3S14 and Na2Ti2Se8. It is shown that a variety of interesting solid-state metal chalcogenides, many of which show low dimensionality, may be synthesized over a range of temperatures. Compounds discussed include K4Hf3Te17 and Cs4Zr3Te16, the series Cu3NbSe4, KCu2NbSe4, K2CuNbSe4, and K3NbSe4, KCuMQ3 and NaCuMQ3 (M = Ti, Zr, Hf; Q = S, Se, Te), Cs0.68CuTiTe4, and CsTiUTe5. The unusual structural features of some of these newly synthesized compounds are discussed.

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DO - 10.4028/www.scientific.net/msf.152-153.35

M3 - Conference article

AN - SCOPUS:0028666322

SN - 0255-5476

VL - 152-5

SP - 35

EP - 42

JO - Materials Science Forum

JF - Materials Science Forum

T2 - Proceedings of the International Symposium on Soft Chemistry Routes to New Materials

Y2 - 6 September 1993 through 10 September 1993

ER -

Reactive flux syntheses at low and high temperatures

Abstract

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