Reactive flux syntheses at low and high temperatures

J. A. Cody*, M. F. Mansuetto, S. Chien, J. A. Ibers

*Corresponding author for this work

Research output: Contribution to journalConference articlepeer-review

18 Scopus citations

Abstract

This paper reviews the reactive flux method for the synthesis of ternary and quaternary metal polychalcogenides, starting with the early synthesis of K4Ti3S14 and Na2Ti2Se8. It is shown that a variety of interesting solid-state metal chalcogenides, many of which show low dimensionality, may be synthesized over a range of temperatures. Compounds discussed include K4Hf3Te17 and Cs4Zr3Te16, the series Cu3NbSe4, KCu2NbSe4, K2CuNbSe4, and K3NbSe4, KCuMQ3 and NaCuMQ3 (M = Ti, Zr, Hf; Q = S, Se, Te), Cs0.68CuTiTe4, and CsTiUTe5. The unusual structural features of some of these newly synthesized compounds are discussed.

Original languageEnglish (US)
Pages (from-to)35-42
Number of pages8
JournalMaterials Science Forum
Volume152-5
DOIs
StatePublished - 1994
EventProceedings of the International Symposium on Soft Chemistry Routes to New Materials - Nantes, Fr
Duration: Sep 6 1993Sep 10 1993

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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