Abstract
The reaction of a macrocyclic Rh(I) complex having hemilabile PO ligands with CI- results in Rh - O bond breakage and yields a Cl-bridged tetranuclear Rh(I) complex, which was characterized by a single-crystal X-ray diffraction study. Reactivity of the complex with CO and halide abstracting agents is described.
Original language | English (US) |
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Pages (from-to) | 789-792 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 27 |
Issue number | 4 |
DOIs | |
State | Published - Feb 25 2008 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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CCDC 683344: Experimental Crystal Structure Determination
Kuwabara, J. (Creator), Ovchinnikov, M. V. (Creator), Stern, C. L. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2008
DOI: 10.5517/ccqy2c2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqy2c2&sid=DataCite
Dataset
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CCDC 683345: Experimental Crystal Structure Determination
Kuwabara, J. (Creator), Ovchinnikov, M. V. (Creator), Stern, C. L. (Creator) & Mirkin, C. A. (Creator), Cambridge Crystallographic Data Centre, 2008
DOI: 10.5517/ccqy2d3, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqy2d3&sid=DataCite
Dataset