Reactivity of dinuclear rhodium(I) macrocycles formed via the weak-link approach

Junpei Kuwabara, Maxim V. Ovchinnikov, Charlotte L. Stern, Chad A Mirkin*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

7 Scopus citations

Abstract

The reaction of a macrocyclic Rh(I) complex having hemilabile PO ligands with CI- results in Rh - O bond breakage and yields a Cl-bridged tetranuclear Rh(I) complex, which was characterized by a single-crystal X-ray diffraction study. Reactivity of the complex with CO and halide abstracting agents is described.

Original languageEnglish (US)
Pages (from-to)789-792
Number of pages4
JournalOrganometallics
Volume27
Issue number4
DOIs
StatePublished - Feb 25 2008

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

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